Calculate the change in enthalpy (ΔH) for 1.0 mol of carbon dioxide (CO2) initially at a volume of 5.00 L and a temperature of 298 K to a final volume of 10.00 L and a temperature of 373 K. Explicitly state all assumptions along with a justification for any and all assumptions made. Express your answer in units of kilojoules per mole (kJ/mol). Assume an ideal gas.
Calculate the change in enthalpy (ΔH) for 1.0 mol of carbon dioxide (CO2) initially at a...
A piston-cylinder arrangement contains Carbon dioxide (CO2) initially at 66 kPa and 400 K, undergoes an expansion process with pressure-volume relationship of PV 1.2 = Costant.to a final temperature of 298 K. Assuming the gas to be an ideal gas, determine the final pressure (kPa), the work done and the heat transfer each in kJ.
Carbon dioxide contained in a piston-cylinder arrangement, initially at 6 bar and 400K, undergoes an expansion to a final temperature of 298 k, during which the pressure-volume relationship if pV^1.2 = constant. Assuming the ideal gas model for the CO2, determine the final pressure, in bar, and the work and heat transfer, each in kJ/kg
Carbon dioxide (CO2) is initially at 11.09 MPa, 330°K and then is compressed to 430°K and 22.17 MPa. a Treating carbon dioxide as an ideal gas: Find the change in specific volume between the initial & final states Find the change in enthalpy between the initial & final states per kmol Find the change in entropy between the initial & final states per kmol b Treating carbon dioxide as a real gas: Use the generalized charts to determine the change...
Carbon dioxide (CO2) is initially at 11.09 MPa, 3300K and then is compressed to 430°K and 22.17 MPa. a Treating carbon dioxide as an ideal gas: Find the change in specific volume between the initial & final states Find the change in enthalpy between the initial & final states per kmol Find the change in entropy between the initial & final states per kmol b Treating carbon dioxide as a real gas: Use the generalized charts to determine the change...
a piston -cylinder device contains 2.5 Kg of carbon dioxide (CO2 ) initially at 100 KPa and 300o C. The carbon dioxide is then compressed to 200 kPa following a process of Pv1.25 =constant. Determine (A) the boundary worked needed for the process (B) The temperature after compression . use Ideal gas state and Pressure in absolute pressure ; R=0.1889 KJ/Kg-K
The standard enthalpy change for the reaction of SO3(g) with H2O(l) to yield H2SO4(aq) is ΔH∘ = -227.8 kJ .? Use the following information S(s)+O2(g)→SO2(g), ΔH∘ = -296.8kJ SO2(g)+12O2(g)→SO3(g) , ΔH∘ = -98.9kJ to calculate ΔH∘f for H2SO4(aq) (in kilojoules per mole). [For H2O(l),ΔH∘f = -285.8kJ/mol]. Express your answer using four significant figures.
1. Calculate the enthalpy change, ΔH, for the process in which 31.6 g of water is converted from liquid at 0.4 ∘C to vapor at 25.0 ∘C . For water, ΔHvap = 44.0 kJ/mol at 25.0 ∘C and Cs = 4.18 J/(g⋅∘C) for H2O(l). 2. How many grams of ice at -16.2 ∘C can be completely converted to liquid at 10.2 ∘C if the available heat for this process is 4.27×103 kJ ? For ice, use a specific heat of 2.01...
Calculate the standard enthalpy of formation of gaseous carbon dioxide (CO2) using the following thermochemical information: 2 C(s) + H2(g) C2H2(g) H = +226.8 kJ 2 C2H2(g) + 5 O2(g) 4 CO2(g) + 2 H2O(l) H = -2599.3 kJ 2 H2O(l) 2 H2(g) + O2(g) H = +571.7 kJ H = _______kJ
The combustion of methane (CH4) at 298.0 K produces carbon dioxide gas (CO2) and liquid water. A constant volume vessel of volume V = 0.807 L is loaded with 1.000 mole of each methane and oxygen. Find the total pressure in bar after the reaction has taken place at 298 K. Use an ICE box, and for now you may assume the reaction goes to completion at 298 K
The standard heat of formation, ΔH∘f, is defined as the enthalpy change for the formation of one mole of substance from its constituent elements in their standard states. Thus, elements in their standard states have ΔH∘f=0. Heat of formation values can be used to calculate the enthalpy change of any reaction. Consider, for example, the reaction 2NO(g)+O2(g)⇌2NO2(g) with heat of formation values given by the following table: Substance ΔH∘f (kJ/mol) NO(g) 90.2 O2(g) 0 NO2(g) 33.2 Then the standard heat...