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Do the titration on Unknown 6 (results are a pH of 13.75 after titration) Give the:...

Do the titration on Unknown 6 (results are a pH of 13.75 after titration)

Give the:

3 letter abbreviation of the amino acid

pka1 (COOH) value?

pka2 (NH3+) value?

pka3 (side chain) value?

pI value?

The only info given is the ph that is 13.75 and 34 ml of titrant was used.

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Answer #1

Since the pH of the solution is 13.75 after titration, it indicates that base has been used to titrate the solution and after titration, the resulting pH has come because of addition of some extra base.

Now among the amino acids, arginine which has the following structure has pKa3 at 12.48. Hence for the titration fo this amino acid, high concentration of base will be required. Therefore the possible amino acid is arginine.

The pKa1 for this is 2.17, the pka2 is 9.04 and pka3 is 12.48. This is known from literature.

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