Exercise 12.1(b) Calculate the zero-point energy of a harmonic oscillator consisting of a rigid CO molecule adsorbed to a metal surface by a bond of force constant 285 N m-1.
Exercise 12.1(b) Calculate the zero-point energy of a harmonic oscillator consisting of a rigid CO molecule...
l Co Zero Point Energy Quantunm Vacuum 0 Harmonic Oscillator The above image shows the harmonic oscillator for a diatomic molecules. The blue line is the zero point energy. What physical phenomenon justifies the existence of this value? How would this potential energy curve change (and the associated vibrations) for a real diatomic molecule (anharmonic oscillation) l Co Zero Point Energy Quantunm Vacuum 0 Harmonic Oscillator The above image shows the harmonic oscillator for a diatomic molecules. The blue line...
Quantum, 1D harmonic oscillator. Please answer in full. Thanks. Q3. The energy levels of the 1D harmonic oscillator are given by: En = (n +2)ha, n=0. 1, 2, 3, The CO molecule has a (reduced) mass of mco = 1.139 × 10-26 kg. Assuming a force constant of kco 1860 N/m, what is: a) The angular frequency, w, of the ground state CO bond vibration? b) The energy separation between the ground and first excited vibrational states? 7 marks] The...
The vibrational absorption spectrum of a diatomic molecule in the harmonic oscillator approximation consists of just one line whose frequency is given by, ν = 1 k . The bond 2π μ length of 12C14N is 117 pm and the force constant is 1630 N m-1. Predict the vibration-rotation spectrum of 12C14N within the harmonic oscillator rigid rotor approximation
The force constant of 79Br79Br is 240 Nm-1. Calculate the fundamental vibrationalfrequency and the zero-point energy of 79Br2 in the harmonic oscillator / rigid rotorapproximation.
Hydrogen molecule bonded to a surface is acting as a quantized harmonic oscillator with a force constant of 300 Nm^-1. a) What is the second to the lowest possible vibrational energy of this system? b) What is the wavefunction of the photon whose energy matches the difference between these two energy levels?
2. The force constant for the CO molecule is 1860 N m-1 a. Calculate the reduced mass of CO. The ses of C and O are 12.0000 amu and 15.994915 amu. b. Calculate the zero-point vibrational energy of CO If this much energy were converted to translational kinetic energy how fast would the molecule be moving c. d. Calculate the average speed for CO at 298 K using the equation we derived for the kinetic theory of gases and compare...
The force constant for the 1H35Cl molecule is 516 N/m. (a) Calculate the vibrational zero-point energy of this molecule. (b) If this amount of energy could somehow be converted to translational energy, how fast would the molecule be moving? (a) E = _____________________________ J (b) v = ___________________________ m/s The moment of inertia, I, of this molecule is 2.644 x 10-47kg m2. What are the frequencies of light corresponding to the lowest energy (c) pure vibrational and (d) pure rotational...
4&5 only thnkyouu :) 3. The force constant for 119F molecule is 966 N/m. a) Calculate the zero-point vibrational energy using a harmonic oscillator potential. b) Calculate the frequency of light needed to excite this molecule from the ground state to the first excited state. 4. Is 41(x) = *xe 2 an eigenfunction for the kinetic energy operator? Is it an eigenfunction for potential energy operator? 5. HCI molecule can be described by the Morse potential with De = 7.41...
2. (10 pts) Hydrogen molecule bonded to a surface is acting as a quantized harmonic oscillator with a force constant of 300 Nm! What is the wavefunction of the photon whose energy matches the difference between these two energy levels? (10 pts=5 points for correct work shown, 2 points for the correct units, and 3 points for correct answer)
(10 pts) The two calculations below pertain to the quantum harmonic oscillator (qho). Relevant expressions for the qho states and energies needed are given by: En-(n +-)ћ1_ and n-AnHn(ye- Two 1g masses are attached by a spring with a force constant k-500 kg/s2. Calculate the zero point energy of this system. How fast would this system have to move to have that much translational energy? a. b. Calculate the wavenumber and wavelength of radiation absorbed when a quantum harmonic oscillator...