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Given that pKa = 3.74 at 25 °C for HCOOH, what is the pH of 0.113...

Given that pKa = 3.74 at 25 °C for HCOOH, what is the pH of 0.113 mol L−1 HCOONa(aq) at 25 °C? What is the equilibrium concentration of HCOOH?

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Answer #1

An ICE table is made

Initial concentration (M) 0.113 0 0
Change in concentration (M) -x +x +x
Equilibrium concentration (M) 0.113-x x x

The base dissociation constant

Since value of Kb is very small, we approximate 0.113-x to 0.113

Hence, the equilibrium concentration of HCOOH is

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