C6H5-COOH + NaOH →
C6H5-NH2 + HCl →
CH3OH + [Ce(NO3)6]2- →
CH3CH2Br + AgNO3 →
(CH3)2CHCHO + H2N-NH-C6H3(NO2)2 →
(CH3)2CHCHO + 2 [Ag(NH3)2]+ 2 OH- →
CH3CH2CH=CHCH2CH3 + Br2 →
(CH3)2C=O + H2N-NH-C6H3(NO2)2 →
C6H5-COOH + NaOH → C6H5-NH2 + HCl → CH3OH + [Ce(NO3)6]2- → CH3CH2Br + AgNO3 →...
72 Laboratory 6 Organic Functional Group Tests 9. Complete the following equations: a. CH,COOH + H,0 + b, CHỊCH,NH, + HO © CHỊCH,CHỊCH,CHẠCH-COOH NaOH d. C,H-COOH + NaOH e. C,H-NH, + HCI f. CH,OH + (Ce(NO) g. CH,CHBr + AgNO, h. CH,COO Ag + HNO, → i. CH,CHO + [Ce(NO3) + j. (CH), CHCHO + HN-NH-C,H,(NO), (2,4-DNPH) k (CH),CHCHO + 2 [Ag(NH,),]* + 20H 1. CH,CH,CH=CHCH,CH, + Br, → m. (CH),C=O + H2N-NH-C,H,(NO), (2,4-DNPH) n. cyclohexane + Br-
7. 8. Na2SO3 + HCI — K,CrO4 + Pb(NO3)2 —> NaC,H,O, + HCl — NaOH + NH4NO3 → 09HHH - .100 ,00 HO, 00 → BiClg + H2S Dan 13. | 14. 15. K,C,04 + HCI — H,PO, + Ca(OH)2 — (NH) CO, + HNO3 - K.CO, + NiBr-
61. What product is finally formed when the initial compound formed from cyclohexanone and pyrrolidine is mixed with allyl chloride and that product is heated and then hydrolyzed? HO ora III A) I B) II C) III D) IV E) V 59. Which reagent would best serve as the basis for a simple chemical test to distinguish between CH3 ? CH3 and M A) NaOI (12 in NaOH) B) Bry/CCL C) CrO3/H2SO4 D) NaHCO3/H20 E) Ag(NH3)2+ 60. What would be...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of all proton resonances (8 pts). Calculate the Unsaturation Index of each compound (4 pts) (30 points total) 30 Unsat. Index = (2C+2-H-X+NY2 = 200 25 e = 2.00 ppm, 4.90 f = 1.27 ppm, 20 720 Compound 18a: C,H,O, singlet, 2H triplet, 3H 127 15 d = 2.66 ppm, a = 7.21 ppm, b = 7.18 ppm, doublet, 2H doublet, 2H C = 4.90...