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How will an increase in pressure affect the following equilibrium? CaO(s) + CO2(g) ⇌ CaCO3(s) ΔH...

How will an increase in pressure affect the following equilibrium? CaO(s) + CO2(g) ⇌ CaCO3(s) ΔH = −176 kJ

Shift toward products. Shift toward reactants. No change. Explain?

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Answer #1

Solid and liquid substances are not affected by change in pressure since they are not involved in equilibrium constant expression Kp because partial pressure of solids and liquids is considered 1.

On increasing the pressure , volume decreases and number of moles increases , since reactant side has 1 gaseous mole and product side side has no gaseous moles. Equilibrium shifts in such a way so as to decrease moles of CO2. Hence equilibrium shifts toward products.

Shifts toward products.

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