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The reaction between lime (CaO(s)) and carbon dioxide (CO2(g)) forms the predominant mineral in limestone, CaCO3(s),...

The reaction between lime (CaO(s)) and carbon dioxide (CO2(g)) forms the predominant mineral in limestone, CaCO3(s), (Delta Hrxn° = −177.1 kJ/mol, Delta Srxn° = −158.2 J/K∙mol). Lime is a key component in making concrete and is made from limestone. What is the minimum temperature required to shift the equilibrium toward lime (CaO(s)) from limestone (CaCO3(s))?

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Answer #1

We know the relation ;

  where is the change in Gibbs free energy , is the change in enthalpy , T is the temperature and is the change in entropy. If = 0 then the system is at the limit of the reaction spontaneity, Thus,

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