What is the role of the Acetic acid in the oxidation of Cyclohexanol to Cyclohexanone? Write...
Homework Answers
The acetic acid contributes the H3O + ion that works as a catalyst in the reaction, since the HOCl ionizes with said ion and contributes the Cl atom that favors the reaction.
It happens:
CH3COOH + HClO = CH3COO- + H2ClO +
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What is the role of the Acetic acid in the oxidation of
Cyclohexanol to Cyclohexanone? Write...
1. [09 pts.] Draw the chemical equations for formation of hypochlorous acid and oxidation of cyclohexanol....
1. [09 pts.] Draw the chemical equations for formation of hypochlorous acid and oxidation of cyclohexanol. (No mechanism) 2. (11 pts.) Show the detailed mechanism for oxidation of cyclohexanol. Show all arrows to indicate movement of electrons. 3. [08 pts.] Briefly explain the roles of sodium hypochlorite and acetic acid in the oxidation of cyclohexanol.
Complete reagent table. thank you! LABORATORY 9 OXIDATION OF CYCLOHEXANOL TO CYCLOHEXANONE TABLE 9.1 Reagent Table...
Complete reagent table. thank you!
LABORATORY 9 OXIDATION OF CYCLOHEXANOL TO CYCLOHEXANONE TABLE 9.1 Reagent Table Cyclohexanol Sodium Acetone Hypochlorite Acetic Acid Cyclohexanone MW (g/mol) 100.20 58.08 74.44 60.05 98.14 mp (C) 16-17 bp (°C) 161 118-119 157 56 density (g/mL) 0.960 1.049 0.970 0.784 0.1 0.78 0.150 6.0 0.3 1.0 mL (6% aq. sol) 1.5 2.5 mmol 1.0 1.6 equiv
Explain the role of the starch iodide test during the oxidation reaction and explain the reaction...
Explain the role of the starch iodide test during the oxidation reaction and explain the reaction that was used to identify the formation of the product in that reaction. *The experiment was Cyclohexanone from Cyclohexanol: Cyclohexanol + NaCl-----Acetic Acid---> Cyclohexanone + NaCl + H2O
Cyclohexanol is oxidized by a mixture of sodium hypochlorite and acetic acid. The solution is treated...
Cyclohexanol is oxidized by a mixture of sodium hypochlorite and acetic acid. The solution is treated with sodium bisulfite and sodium hydroxide, before the product is extracted into dichloromethane. The organic layer was dried over potassium carbonate, decanted, and the product was obtained when the solvent was evaporated.
Drag and drop the chemical wastes generated in this reaction into the appropriate container.
[08 pts.] Briefly explain the roles of sodium hypochlorite and acetic acid in the oxidation of...
[08 pts.] Briefly explain the roles of sodium hypochlorite and acetic acid in the oxidation of cyclohexanol. sodium hypochlorite and acetic aut are added together to create the hypochlurous act, which used to protorate the oth grap on cyclo hexarod. [12 pts.] Draw the major product for each of the following oxidation reactions. кон Na CrO; H2SO4, H,0 Na Cr2O7 H2SO4, H20 CHO PCC
The procedure for the oxidation of cyclohexanol produces not only cyclohexanone, but also a small amount...
The procedure for the oxidation of cyclohexanol produces not only cyclohexanone, but also a small amount of cyclohexene. How would the 1H-NMR spectrum of cyclohexene differ from that of cyclohexanone? Explain your reasoning
Write the mechanism of oxidation of an alcohol with sodium hypochlorite in the presence of glacial...
Write the mechanism of oxidation of an alcohol with sodium hypochlorite in the presence of glacial acetic acid. Indicate, which species is an electron acceptor.
chemical reaction 4. Which Cyclohexanol oxidation method is "cleaner" (safer for the environment): the one using...
chemical reaction 4. Which Cyclohexanol oxidation method is "cleaner" (safer for the environment): the one using dichromate or the one using Clorox? Why (answer in terms of the waste products generated in these reactions)? 5. Why did we extract the Cyclohexanone in a three step extraction (with 10 ml, 8 ml and 7 ml Ether) rather than in one step (with 25 ml Ether)? 6. What does it mean if the IR spectrum of your final product (Cyclohexanone) shows a...
give a reaction mechanism for the synthesis of cyclohexanone from cyclohexanol when the oxidizing agent is...
give a reaction mechanism for the synthesis of cyclohexanone from cyclohexanol when the oxidizing agent is hypochlorous acid.
Write a balanced chemical equation for the oxidation reaction between Caro’s acid (H2SO5) and CN– ion...
Write a balanced chemical equation for the oxidation reaction between Caro’s acid (H2SO5) and CN– ion in aqueous solution.
1. [09 pts.] Draw the chemical equations for formation of hypochlorous acid and oxidation of cyclohexanol. (No mechanism) 2. (11 pts.) Show the detailed mechanism for oxidation of cyclohexanol. Show all arrows to indicate movement of electrons. 3. [08 pts.] Briefly explain the roles of sodium hypochlorite and acetic acid in the oxidation of cyclohexanol.
Complete reagent table. thank you!
LABORATORY 9 OXIDATION OF CYCLOHEXANOL TO CYCLOHEXANONE TABLE 9.1 Reagent Table Cyclohexanol Sodium Acetone Hypochlorite Acetic Acid Cyclohexanone MW (g/mol) 100.20 58.08 74.44 60.05 98.14 mp (C) 16-17 bp (°C) 161 118-119 157 56 density (g/mL) 0.960 1.049 0.970 0.784 0.1 0.78 0.150 6.0 0.3 1.0 mL (6% aq. sol) 1.5 2.5 mmol 1.0 1.6 equiv
Cyclohexanol is oxidized by a mixture of sodium hypochlorite and acetic acid. The solution is treated with sodium bisulfite and sodium hydroxide, before the product is extracted into dichloromethane. The organic layer was dried over potassium carbonate, decanted, and the product was obtained when the solvent was evaporated.
Drag and drop the chemical wastes generated in this reaction into the appropriate container.
[08 pts.] Briefly explain the roles of sodium hypochlorite and acetic acid in the oxidation of cyclohexanol. sodium hypochlorite and acetic aut are added together to create the hypochlurous act, which used to protorate the oth grap on cyclo hexarod. [12 pts.] Draw the major product for each of the following oxidation reactions. кон Na CrO; H2SO4, H,0 Na Cr2O7 H2SO4, H20 CHO PCC
chemical reaction 4. Which Cyclohexanol oxidation method is "cleaner" (safer for the environment): the one using dichromate or the one using Clorox? Why (answer in terms of the waste products generated in these reactions)? 5. Why did we extract the Cyclohexanone in a three step extraction (with 10 ml, 8 ml and 7 ml Ether) rather than in one step (with 25 ml Ether)? 6. What does it mean if the IR spectrum of your final product (Cyclohexanone) shows a...
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