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A 0.52900.5290 g solid sample containing a mixture of LaCl3LaCl3 (molar mass = 245.26 g/mol) and...

A 0.52900.5290 g solid sample containing a mixture of LaCl3LaCl3 (molar mass = 245.26 g/mol) and Ce(NO3)3Ce(NO3)3 (molar mass = 326.13 g/mol) was dissolved in water. The solution was titrated with KIO3KIO3, producing the precipitates La(IO3)3La(IO3)3 and Ce(IO3)3Ce(IO3)3. For the complete titration of both La3+La3+ and Ce3+Ce3+, 42.2742.27 mL of 0.12130.1213 M KIO3KIO3 was required. Calculate the mass fraction of LaLa and CeCe in the sample.

mass fraction La:______ g LA/ g Sample

mass fraction Ce:______ g Ce/ g Sample

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Answer #1

First mass of LaCl3 is calculated , then moles of LaCl3 is same as moles of La. For calculations see the picture below:

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