Draw the molecules given below, give the ligand geometry (octahedral, tetrahedral, etc…), and determine the metal oxidation state, d-electron count, total electron count (17, 18, etc…).
a) [Pd(PPh_3)_4]
b) [Co(tren)(SH)]+
c) [PtCl_4(bpy)]
d) PdI_2(PPh3)_2
e) [FeCl4]^2-
Draw the molecules given below, give the ligand geometry (octahedral, tetrahedral, etc…), and determine the metal...
The transition metal ion, Fe(III), can form octahedral or tetrahedral complexes depending on the ligand it binds to. (a) (i) [Fe(CN)6]3- is a strong field octahedral complex of Fe(III). Draw a labelled orbital energy level diagram that shows both the splitting of the d-orbitals and their electron occupancy in [Fe(CN)6]. (3 marks) (ii) Fe(III) can also form tetrahedral complexes, most of which are weak field. Draw a labelled orbital energy level diagram that shows both the splitting of the d-orbitals...
For each of the following complexes draw the structure, determine the electron count at the metal centre (use the neutral ligand method) and give the oxidation state of the metal (0) [Tan-CsHs)-(CH3)3] (11) [Ni(n-C3Hs)(PPh3>(CO)2] (111) [Mn(n-CHS)(CO)3]* [Ru(PMe3)2(CHPh)C12] (v) [Co(H2-COXCO);}2 Assume a direct Co-Co bond in (v) Explain, using suitable diagrams, the Berry pseudorotation mechanism
Please give a detailed explanation. 18.15 The Wilkinson catalyst chlorotris(triphenylphosphine)rhodium(I), CIRh(PPha), brings about the catalytic hydrogenation of an alkene in homogeneous solution: R R CIRh(PPh3)3 C=C + H - RCH CHR (18.41) HH (a) Using the following mechanistic steps as your guide, draw structures of the transition-metal complexes involved in each step. Give the electron count and the metal oxidation state at each step. 1. oxidative addition of H, to the catalyst 2. ligand substitution of one PPhz by the...
5. The [NI(CN)412- ion has a square-planer geometry, whereas the INca diagrams (with d-orbital labels) for these twe complexes and determine if the compound is paramognetic or diamognet ion is tetrahedral. Drow the crystal field splitting 6. The absorption maximum for the complex ion (Co( Hale ccurs at 410 m. Predict the coler of this complex.Explain your reasoning. the Lewis structure of each and state whether the following are monodentate or bide ntate ligands a. c2042 (oxalate ion, ox) b,sar...
2. A piece of sodium metal reacts completely with water as follows: 2Na(s) + 2H2O(l) à 2NaOH(aq) + H2(g). The hydrogen gas generated is collected over water at 25.0oC. The volume of the gas is 252mL measured at 1.00atm. Calculate the number of grams of sodium used in the reaction. (Vapor pressure of water at 25oC = 0.0313atm). a. 0.23g b.0.25g c. 0.474g d. 0.459g 3. Write the ground state electron configuration for Iron. a. [Kr]5s24d105p5 b. [Rn]7s1 c. 1s22s22p5...
1. The reaction 6f propane with oxygen follows the reaction below: Equation1 ) Balance Equation 1 above i) is the above reaction endothermic or exothermic? Enstem i) Classify the reaction above as combination, single displacement, double displacement, decomposition or combustion. comba How much heat was produced in Equation 1 if it can heat 100 g of water from 32 °C? to 40 Is the energy in propane potential or kinetic energy? P。hhi vi) Given that 1 mole of propane produces...
biochemistry if you could please help me answer the following questions! EFT i 11) (6 pts) Which types of symmetry are possible for a protein with six (6) identical subunits? (Select all correct answers) a) cyclic C b) cyclic C3 c) dihedral D2 d) dihedral D e) octahedral o f) icosahedral ро, Yo₂ - pO₂+ Pso 12) (6 pts) What is the fractional saturation of oxygen binding to myoglobin when the partial pressure of oxygen is 1.5 torr and dissociation...