Which of the following sets of parameters are altered when a reaction is carried out in the presence of a catalyst? Select one:
A. ΔG°, ΔH°, Keq
B. ΔH°, ΔS°, krate
C. ΔH°, ∆S°, Ea
D. ΔG°, krate, Keq
E. Ea, free energy of activation, krate
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Which of the following sets of parameters are altered when a reaction is carried out in...
Given which of the following sets of thermodynamic parameters is a reaction spontaneous only at higher temperatures? A) ΔH < 0 and ΔS < 0 B) ΔH < 0 and ΔS > 0 C) ΔH > 0 and ΔS > 0 D) ΔH > 0 and ΔS < 0 ---------------------------------------------------------------------------------------------------------------------------- A galvanic cell is constructed using a zinc electrode immersed in a 1.0 M Zn2+ solution and a silver electrode immersed in a 1.0 M Ag+ solution. What is the...
1) In a biochemical reaction in which ΔH < 0 and ΔS > 0, Select one: a. the reaction is spontaneous b. the reaction is endothermic c. the reaction is endergonic d. ΔG is positive 2) NAD+ and FAD are often referred to as Select one: a. redox proteins b. polymers c. reduced dinucleotides d. electron-carrying coenzymes 3) What is [P]/[R] when ΔG = ΔG°´? Select one: a. –1 b. 0 c. 1 d. 2.3 4) For the binding reaction...
For reactions carried out under standard-state conditions, the equation ΔG = ΔH − TΔS becomes ΔG° = H° − TΔS°. Assuming ΔH° and ΔS° are independent of temperature, one can derive the equation: ln( K2 K1 ) = ΔH° R ( T2 − T1 T1T2 ) where K1 and K2 are the equilibrium constants at T1 and T2, respectively. Given that at 25.0°C, Kc is 4.63×10−3 for the reaction N2O4(g) longrightleftarrow 2NO2(g) ΔH° = 58.0 kJ/mol calculate the equilibrium constant...
When the following redox reaction is carried out in a voltaic cell, the standard cell potential, E°cell, is 0.93 V. What is ΔG° for this reaction at a temperature of 298.15 K? Pb(s) + 2 Ag+(aq) → Pb2+(aq) + Ag(s) A. -180 kJ B. -90 kJ C. 90 kJ D. 180 kJ
8. (20 points) Consider the following mechanism, with the accompanying energy diagram, which has been suggested for the following overall reaction in the presence of a Cl catalyst: 03 +0 202 Step 1: Step 2: 03 + Cl → OCl + O2 OCl + 0 + 02 + Cl +---Ea, Energy - - - - AHrxn --- - Reaction progress- A. Based on the energy diagram, which step is rate limiting? Which step is the fastest? (4 Points) B. Identify...
For a particular reaction, the change in enthalpy is −9kJmole and the activation energy is 13kJmole. The enthalpy change (ΔH) and activation energy (Ea) for the catalyzed reaction could be which of the following? Select the correct answer below: A)−9kJmole,5kJmole B)−9kJmole,19kJmole C)−14kJmole,5kJmole D)−14kJmole,−13kJmole
3) Answer all parts of the following question. a. The reaction: Al(s) + Fe2O3(s) → Fe(s) + Al2O3(s) has ΔH = -847.6 kJ and ΔS = -41.3 J/K at 25°C. Calculate ΔG and determine if it is spontaneous. b. Above what temperature does the following reaction become nonspontaneous? FeO(s) + CO(g) → CO2(g) + Fe(s) ΔH = -11.0 kJ; ΔS = -17.4 J/K c. Find ΔSsurr and predict whether or not this reaction will be spontaneous at 398 K. NH3(g)...
A reaction profile (not to scale!) for the reaction C2H4 +
HClC2H5Cl is shown below:
Which of the following are true? Choose all that apply.
1. The value of Ea in the presence of a catalyst would be larger
than 205 kJ. E is positive.
2. The energy of the products is lower than the energy of the
reactants.
3. The value of E in the presence of a catalyst would be smaller
than -70.0kJ
4. The magnitude of Ea...
Free-energy change, ΔG∘, is related to cell potential, E∘, by the equation ΔG∘=−nFE∘ where n is the number of moles of electrons transferred and F=96,500C/(mol e−) is the Faraday constant. When E∘ is measured in volts, ΔG∘ must be in joules since 1 J=1 C⋅V. Calculate the standard cell potential at 25 ∘C for the reaction X(s)+2Y+(aq)→X2+(aq)+2Y(s) where ΔH∘ = -679 kJ and ΔS∘ = -195 J/K .
An acid-catalyzed irreversible liquid-phase reaction A B is carried out adiabatically in a CSTR. The reaction is second order in A. The feed is equimolar A and solvent (S, which contains catalyst), and enters the reactor at a total volumetric flow rate of 10 dm3/min at a concentration of A of 4 mol/L. The feed enters at 300 K. The product and reactant heat capacities are 15 cal/(mol°C), the solvent is 18 cal/(mol°C). The reaction rate constant at 300 K...