Which of the compounds contain chiral centers?
1-bromobutane
2-bromobutane
1,2-dibromobutane
1,3-dibromobutane
1,4-dibromobutane
2,3-dibromobutane Chirality and Enantiomers
we identify the given compound is chiral or achiral compound based on structure if carbon is attached with four different groups that is chiral carbon
Which of the compounds contain chiral centers? 1-bromobutane 2-bromobutane 1,2-dibromobutane 1,3-dibromobutane 1,4-dibromobutane 2,3-dibromobutane Chirality and Enantiomers
5. Do the following compounds have any chirality centers? Which one is chiral? If has chirality, how m stereoisomer does it have? (a) Cis- 1,2-dimethylcyclobutane (b) Penicilin G CH3 OH 2
(d) Do the following compounds have any chirality centers? Which one is chiral? If has chirality, how many stereoisomer does it have? (a) Cis- 1,2-dimethylcyclobutane (b) Morphine N- CHI OH Y CU HU
9. Draw the structural formulas for the following compounds: a. 1-bromobutane b. 2-bromobutane c. 1, 2-dibromobutane d. 1, 3-dibromobutane e. 1, 4-dibromobutane f. 2, 3-dibromobutane
3.14 Which compounds contain chiral centers? (a) 2-Chloropentane (b) 3-Chloropentane (c) 3-Chloro-1-pentene (d) 1,2-Dichloropropane 3.18 Mark each chiral center in the following molecules with an asterisk. How many stereo isomers are possible for each molecule? CH COOH CH 0 (a) CH CCH=CH, (b) HCOH (c) CH,CHCHCOOH (d) CH,CCH.CH OH CH NH CH,OH OH CH,COOH (e) HCOH () CHCH.CHCHECH, (g) HOCCOOH CH,OH CH,COOH
1. Identify all the chiral centers in the y all the chiral centers in the molecule below: 2. For each of the pairs of compounds, de indicate if they are identical, enantiomers, diastereomers, constitutional isomers or different compounds. 3. Identify the chiral centers in the diastereomers below and label each as R or S.
3. (4 pts) Complete the Fischer projection drawn below by adding the four substituents to the chiral carbon of (s)-2-methyl-3-bromo-hexane. 4. (4 pts) Draw a wedge and dash structure representing (1R 2R,3S)-1,2- dichloro3-ethylcyclohexane. 5. (4pts) 2-bromobutane is shown below. Is this (R)-2-bromobutane or (S)-2 bromobutane? 6. (6 pts) For each chiral carbon in ascorbic acid (vitamin C), shown below, assign Ror S to each stereocenter. How many stereoisomers of ascorbic acid are possible? OH HO ОН 7. (9 pts) (Are...
Which of the following compounds is the most stable? Which of the following compounds is the most stable? (E)-2-methyl-1,3-pentadien 2-methyl-2,3-pentadiene 2-methyl-1,4-pentadiene (Z)-2-methyl-1,3-pentadiene 2-methyl-1,2-pentadiene
please help with this page! CHEM211-Summer 2019 Stereochemistry Part 2) Homework 4 1) What type of isomers are CH3CH2OCH3 and CH3CH CH2OH? constitutional B) symmetrical conformational C) configurational E) stereochemical CH сн What is the relationship between the following compounds? 2) HCCI and H CHCI CH constitutional isomers diastercomers superimposable without bond rotation B) enantiomers D) conformational isomers A) C) E) 3) What is the relationship between the structures shown below? diastercoma constitutional isomers conformational isomers sonfigurational isomers enantiomers A)...
1. Sketch the NMR spectrum you would expect to find each of the following compounds. a) 1-bromobutane b) 2,2-dibromobutane c) 1-butanol d) 2,2,3,3-tetrabromobutane e) butane ) 1,1,4-tribromobutane g) 1,4-dibromobutane h) 1,1,1-tribromobutane i) vinyl bromide j) 1,1-dibromoethene k) cis-1,2-dibromoethene 1) trans- 1,2-dibromoethene n) 2-methyl-2-butene m) allyl bromide
1. Is 1,3-dichloro-1,2-propadiene chiral? Why or why not? Does it have stereocenters? 2. Why is it not possible to determine in which direction a compound rotates light based upon the R or S prefix? Please explain