Complete the table
Formula | Structure | Oxidation state of Metal | Charges of complex | d electron count |
[Ti(H2O)4Cl2] | ||||
fac-[Mo(NH3)3(OH)3]+ | ||||
trans-[Ni(H2O)2Cl2]2+ | ||||
cis-[Cr(C2O4)2(py)2]2- | ||||
delta-[Ni(acac)3] |
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Complete the table Formula Structure Oxidation state of Metal Charges of complex d electron count [Ti(H2O)4Cl2]...
Complete table C.N is coordination number O.N is Oxidation number Complex Formula C.N O.N of the metal Cationic or anionic complex Name of metal complex K4[Ni(CN)4] [Cr(OH2)4Cl2]Cl Na3[Co(C2O4)3] [CoCl2(en)2]F [Co(P(CH3)3)4]2(SO4)3 [Fe(NH3)6]SO4 Na2[MoOCl4] [Cr (NH3)6]Cl3 [Zn(OH)4]-2 [V(OH2)6](NO3)3
Determine the oxidation state and valence d electron count for the metal ion in the coordination complex [Ru(NH3)6]Cl2. For the oxidation state enter your answer in form "charge value" (for example "+2").
Please answer all of the following: a) Give the correct IUPAC name and sketch the structure of the transition metal complex for each of the following compounds. If multiple stereoisomers are possible, give both names and structures: 1) [Pt(NH3)2Cl2] 2) [Cr(NMe3)4Br2]PF6 3) K[Co(edta)], where H4(edta) = ethylenediaminetetraacetic acid 4) [Ir(CO)Cl(PPh3)2] 5) Hg[Co(NCO)4] 6) [Fe(acac)3], where H(acac) = acetylacetone 7) [Co(NH3)6]3+[Cr(CN)6]3- 8) [{Co(NH3)5}2(μ-OH)]Cl5 9) [TiCl3(thf)3], where thf = tetrahydrofuran 10) [Ru(bpy)2Cl2], where bpy = 2,2’-bipyridine 11) V(O)(acac)2, where H(acac) = acetylacetone...
For Cr(CO)3(C6H6) Write the: i) Structure ii) Formula iii) Metal Oxidation State iv) Valence electron count Thanks.
4. Determine the metal oxidation state, d electron count, and total electron count for the following compounds: a. Cp2TiCl2 b. [Cp2Co]+ c. [Mo(N2)2(dmpe)2] d. [ReO2(CO)4]+ ZEZ Ph2 Ph2 L PINTIMO Mome * Re nel ZEZ- Ph = phenyl
For Rh(Cl)(P(C6H5)3)3 Write the: i) Structure ii) Formula iii) Metal Oxidation State iv) Valence electron count Thanks.
2. Indicate i. the metal oxidation state, ii. d-electron count, and iii. coordination number (CN) for the following complex (12 Points). a. Anti-cancer drug b. [Fe S4(SR)] SR Fe COS i. ii. ii. iii. iii. 3. Draw the metal coordination structure of carbonic anhydrase enzyme. Clearly show the 3-D geometry round the metal center. (6 Points)
1- Draw the molecular orbital diagram of transition metal ion in high-spin Mn(H2O)4(OH)2 complex, also determine the number of unpaired electron. 2- Draw the molecular orbital diagram of transition metal ion in low-spin [Cr(en)2(NH3)2].Cl2 complex, also determine the number of unpaired electron. 3- Draw the molecular orbital diagram of transition metal ion in high-spin K.[Mn(CO)3(OH)3] complex, also determine the number of unpaired electron.
5. For each of the following transition metal complexes, give (i) the d-electron count, (ii) the approximate shape of the complex, and (iii) an energy level diagram showing the splitting and filling of the d-orbitals. (a) [Os(CN)6]3- (b) cis-PtCl2(NH3)2 (c) [Cu(NH3)4]*
2. Indicate i. the metal oxidation state, ii. d-electron count, and iii. coordination number (CN) for the following complex (12 Points). a. Anti-cancer drug b. [Fe4S4(SR)4]2- SR S > Fe Cmos i. i. ii. ii. iii. 5. Draw the metal coordination structure of carbonic anhydrase enzyme. Clearly show the ? geomet 21