Question

The reaction N2(g) + O2(g) ⇄ 2 NO(g) contributes to air pollution whenever a fuel is...

The reaction

N2(g) + O2(g) ⇄ 2 NO(g)

contributes to air pollution whenever a fuel is burned in air at a high temperature, as in a gasoline engine. At 1500 K, Kc = 1.0×10-3. Suppose a sample of air has [N2] = 0.70 mol/L and [O2] = 0.20 mol/L before any reaction occurs. Calculate the equilibrium concentrations of reactants and products after the mixture has been heated to 1500 K.

[N2] = M

[O2] = M

[NO] = M

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Answer #1

FIRST CONSTRUCT THE ICE TABLE AND THEN SUBSTITUTE THE VALUES IN KC EXPRESSION AND YOU CAN GET THE X VALUE FROM THIS CALCULATE THE EQUILIBRIUM CONCENTRATIONS
         N2   +    O2   ------------------------> 2 NO

I       0.70       0.20                                     0

C      -X           -X                                      +2X

E    (0.70-X)   (0.20-X)                             2X

Kc = [NO]2 / [N2][O2]

1.0*10-3 = [2X]2 / [0.70-X][0.20-X]

1.0*10-3 * [0.70-X][0.20-X] = [2X]2

solving for X => 0.0058 M

at equilibrium [N2] = (0.70-X) =(0.70-0.0058) = 0.6942 M

                        [O2] = (0.40-X) = (0.40-0.0058) = 0.3942 M

                        [NO] = 2X = 2*0.0058 = 0.0116 M

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