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In pairs; Let’s say you add 10.0 g PbCl2 (s) to 1.0 L of water. Even...

  1. In pairs; Let’s say you add 10.0 g PbCl2 (s) to 1.0 L of water. Even though PbCl2 is ‘insoluble’, a fraction of the solid will dissolve.

    1. Write out the chemical equilibrium for the dissolution of PbCl2 in water.

    2. The Ksp for PbCl2 is 1.7 x 10-4. Calculate how many grams of PbCl2 will dissolve in the solution.

    3. Your lab partner claims that by adding NaCl to the solution, thus increasing [Cl-] and forcing the equilibrium back toward PbCl2 (s), they can precipitate out ALL of the PbCl2 (s) that dissolved. You disagree, claiming that some Pb2+ will always remain in solution, no matter how much NaCl is added. Who is correct? Why?

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