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6. The ozone content in polluted air can be determined by an iodometric titration. The air...

6. The ozone content in polluted air can be determined by an iodometric titration. The air sample is bubbled through a buffered KI solution at a rate of 2.8 L/min for 1.5 hr. The density of the air sample is 1.17 g/L. The ozone is reduced by the iodide in the solution according to the following reaction.

O3 g+3 I- aq+2 H+ aq → O2 g+ I3- aq+H2O l

The resulting I3– is titrated with 0.00265 M Na2S2O3 requiring 9.84 mL to reach the endpoint.

2 S2O32- aq+I3- aq → S4O62- aq+3 I- aq

Determine the ozone content of the air sample in ppm (mg O3/kg air). (5 pts)

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