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Two experiments were conducted in a bomb calorimeter. The first one to determine the heat capacity...

Two experiments were conducted in a bomb calorimeter. The first one to determine the heat capacity of the calorimeter, the second to determine the heat of combustion of the carcinogenic substance benzene (C6H6). In the first experiment, the temperature rises from 22.37degrees C to 24.68degrees C when the calorimeter absorbs 5682 J of heat. the second experiment, the comustion of 0.258g of benzene increases the temperature from 22.37degreesC to 26.77degreesC. Determine the heat of combustion for 1 mol of benzene.

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Answer #1

Question 1  

determine the heat capacity of the calorimeter

heat capacity of the calorimeter = 5682 Joules / (24.68 degreesC - 22.37 degreesC) = 2459.74 J/degreesC

heat capacity of the calorimeter = 2459.74 J/degreesC

Question 2

Temperature change when benzene in combusted = 26.77 DegreesC - 22.37 DegreesC = 4.4 DegreesC

The amount of heat released =    2459.74 J/degreesC x 4.4 DegreesC = 10822 Joules or 10.822 Kilo Joules

Moles of benzene combusted = 0.258 gm / 78 gm /mol = 0.00330 Moles

heat of combustion for 1 mol of benzene = 10.822 Kilo Joules / 0.00330 Moles = 3271.769 Kilo Joules / Moles

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