Question

In a collision of sufficient force, automobile air bags respond by electrically triggering the explosive decomposition of sodium azide (NaN3) to its elements. A 43.398 g sample of sodium azide was decomposed, and the nitrogen gas generated was collected over water at 22°C. The total pressure was 798.8 mmHg. How many liters of dry N2 were generated?

An atmospheric chemist studying the pollutant SO2 places a mixture of SO2 and O2 in a1.14 L container at 825.7 K and 2.3 atm. When the reaction occurs, gaseous SO3 forms, and the pressure falls to 1.26 atm. How many moles of SO3 form?

An environmental engineer analyzes a sample of air contaminated with sulfur dioxide. To a 466.03 mL sample at 727.1 torr and 46.9°C, she adds 20.58 mL of 0.01 M aqueous iodine, which reacts as follows:

SO2(g) + 2(aH20 HSO4 (aq) I(a)H(a unbalanced)

Excess I2 reacts with 13 mL of 0.014 M sodium thiosulfate:

What is the volume % of SO2 in the air sample?

By what factor would a scuba diver's lungs expand if she ascended rapidly to the surface from a depth of 127.8 ft without inhaling or exhaling? If an expansion factor greater than 1.74 causes lung rupture, how far could she safely ascend from 127.8 ft without breathing? Assume constant temperature (d of seawater = 1.094 g/mL; d of Hg = 13.802 g/mL). Hint: The pressure at the surface is 1.00atm

Acrylic acid (CH2doublebond.png CHCOOH) is used to prepare polymers, adhesives, and paints. The first step in making acrylic acid involves the vapor-phase oxidation of propylene (CH2doublebond.png CHCH3) to acrolein (CH2doublebond.png CHCHO). This step is carried out at 398.5°C and 4.8 atm in a large bundle of tubes around which a heat transfer agent circulates. The reactants spend an average of 1.5 s in the tubes, which have a void space of 98.5 ft3. How many mols of propylene must be added per hour in a mixture whose mole fractions are 0.07 propylene, 0.35 steam, and 0.58 air?

In the 19th century, J. B. A. Dumas devised a method for finding the molar mass of a volatile liquid from the volume, temperature, pressure, and mass of its vapor. (next column). He placed a sample of such a liquid in a flask that was closed with a stopper fitted with a narrow tube, immersed the flask in a hot water bath to vaporize the liquid, and then cooled the flask. Find the molar mass of a volatile liquid from the following:

Mass of empty flask = 65.347 g

Mass of flask filled with water at 25°C = 327.4 g

Density of water at 25°C = 0.997 g/mL

Mass of flask plus condensed unknown liquid = 65.739 g

Barometric pressure = 104.5 kPa

Temperature of water bath = 99°C

SO2(g) + 2(aH20 HSO4 (aq) I(a)H(a unbalanced)



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p ㅋ23.iterr T-4.9c 464 0.01M, 00.S2 9 pxas 2.058-16-182-10()2.32-10ul 24-10 095035 0.95G구 V S02): 6.53-10 んRrarlwn m (lab)- 43.312 11m 시2 : nNoN) n (%) т-22°C MW (N2) 28.01 tlu rads 43 :3n Alo Als Mul시) -62.303 T-22C- 2 912.9 (-23.0-0.032 am PV-MRT /v RT 2.3oa 1.14K 0.032 .3 n= 2.422 7.31 pasSLu 0.082 K.825. 0.02d

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