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1. Some standard reduction potentials at 25 C are: E 0.337 V for Cu* (a) 2e- Cu(s) E" =-0.1 26 V ...
Given: Zn2+ (aq) + 2e Zn(s); E--0.76 V Cu²+ (aq) +20 Cu(s); E° -0.34 V What is the cell potential of the following electrochemical cell at 25°C? Zn(s) | Zn2+(1.0 M) || Cu2+(0.0010 M) Cu(s) a) greater than 1.10 v b) between 0.76 and 1.10 V c) less than 0.42 V d) between 0.00 and 0.76 V e) between 0.34 and 0.76 V
Standard reduction half-cell potentials at 25°C E (V) E (V) 1.50 -0.45 0.80 -0.50 0.77 -0.73 0.52 -0.76 0.34 -1.18 Half-reaction Aut (aq) + 3e +Au(s) Ag+ (aq) + +Ag(s) Fe3+ (aq) +34 Fo+ (aq) Cut(aq) + Cu(s) Cu²+ (aq) + 2e +Cu(s) 2H+ (aq) - 2e +H2 (6) Fe3+ (aq) + 3e Fe(s) Pb2+ (aq) + 2e →Pb(s) Sn-(aq) + 2e +Sn(s) Ni2+ (aq) + 2e →Ni(s) Co2(aq) +2e + Co(s) ca? (aq) + 2e +Cd(s) 0.00 Half-reaction Fe(aq)...
Constants The following values may be useful when solving this tutorial. Constant Value E∘Cu 0.337 V E∘Zn -0.763 V R 8.314 J⋅mol−1⋅K−1 F 96,485 C/mol T 298 K Part A Part complete In the activity, click on the E∘cell and Keq quantities to observe how they are related. Use this relation to calculate Keq for the following redox reaction that occurs in an electrochemical cell having two electrodes: a cathode and an anode. The two half-reactions that occur in the...
4. Zn2+(aq) + 2e Zn(s) E = -0.762 V Ag+ (aq) + e # Ag(s) E = 0.799 V Determine the voltage of the galvanic cell generated from these two half reactions, and calculate E of the cell when Zn2+ (aq) = 0.0100 M and Ag+ (aq) = 0.900 M at 25°C. Report the value of E
E° (cal.) E° (exp.) 1. Fe(s)| Fe2+ (1 M) || Cu2+ (1 M) | Cu(s) 0.775 V 2. Pb(s) Pb2+ (1 M) || Cu2+ (1 M) Cu(s) 0.461 V 3. Sn(s) | Sn2+ (1 M) || Cu2+ (1 M) | Cu(s) 0.472 V 4. Zn(s) | Zn2+ (1 M) || Cu2+ (1 M) Cu(s) 1.095 V 5. Zn(s) | Zn2+ (1 M) || Cu2+ (1 M + NH3) | Cu(s) 0.928 V a) The Nernst equation for the cell in...
(a) Use the standard reduction potentials at 25° C in Table 18.1 in Tro, Fridgen and Shaw, and calculate the standard emf E° of an electrochemical cell described by the following reaction: Cu + Zn2+ --> Cu2+ + Zn (b) What is the value of E if the concentration of Zn2+ is 8.03 x 10-6 and the concentration of Cu2+ is 6.09 x 10-5? (c) If E = -0.90 V and Zn2+ = 0.10 M, what is the concentration of...
4. (a) Use the standard reduction potentials at 25° C in Table 18.1 in Tro, Fridgen and Shaw, and calculate the standard emf E° of an electrochemical cell described by the following reaction: 3 Zn + 2 Cr3+ + 2 Cr + 3 Zn? (b) What is n? (c) What is AGº for this reaction at 25°? (d) What is the equilibrium constant for this reaction at 25°? TABLE 18.1 Standard Reduction Potentials at 25°C EV) 2.87 1.61 1.51 1.36...
10. Consider the standard potential data shown below. va* + 2e-Ⓡ v E' =-1.18 V Cu + le ® Cut E* = 0.15 V -E° E Ech Use the above data to determine the standard emf for the reaction shown below. Is the reaction Spontaneous? V + 2cuva + 20 (a) Ex--1.03 V therefore the reaction is not spontaneous. (b) Ed. = 1.03 V therefore the reaction is spontaneous. = 1.33 V therefore the reaction is spontaneous. (d) Ex=-1.33 V...
A galvanic cell based on the following reactions Cu 2+ (aq) + 2e- + Cu(s) E°=0.339 V (AD + 14H(aq) + 6e-4 2Cr 3+(aq) + 7 H2O(1) Eo=1.330 V a) Write the overall cell reaction and determine its voltage. b) If the E value of the galvanic cell is 1.2 le of the galvanic cell is 1.254 V, calculate the pH of the cell when [Cu2+]=0.00010 M, Cr-0,2-1=0.00460 M, Cr3+1=1.0x102 M. The Nerst equation is E=E - (0.0592/n)logQ
Given the following standard reduction potentials: H^+ (aq) + 2e^- rightarrow H_2(g) E degree = 0.00 V Fe^3+ (aq) + 2e^- rightarrow Fe(s) E degree = -0.43 V (a) What is the cell potential by combining the above two half-reactions to make a working voltaic cell (same as galvanic cell)? (b) Which species will be oxidized in anode? Write the half-reaction for the anode. (c) Write the overall reaction and balance the chemical equation for this working voltaic cell. (d)...