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how do you show the derivation?

Show the deruaton of equation Peq Astd L std [FeNCS2.hq. A Х[FeNCS2.1.d(2) The conscentration of FeNcs FeNcsJ ) in he sandard
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Answer #1

From Beer Lambert's Law, the absorbance of a substance is given by

A=\epsilon lC

where \epsilon is the molar extinction coefficient of the substance, l is length of sample tube, C is concentration of substance which is also denoted with [substance]

Hence, the equation for [FeNCS]2+ is written as

2+

As absorbance varies with concentration,

For equilibrium concentration of     FeNCS12 eq, Beer Lamberts law is written as

dFeNCSe eq 1

For standard concentration of FeNCS2+ , Beer lamberts law is written as

std eq 2

From both the equations, we get

Astd El std

Therefore,

Ae eq Astd std

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