Using Kapustinskii equation, determine the lattice energy of a hypothetical compound NaCl2. Assume the sum of ionic radii to be 253 pm. If the second ionization energy of Na is 4562 kJ/mol, what would be the enthalpy of formation of that compound?
Using Kapustinskii equation, determine the lattice energy of a hypothetical compound NaCl2. Assum...
Determine the lattice energy of MX2. Consider an ionic compound, MX2, composed of generic metal M and generic, gaseous halogen X. The enthalpy of formation of MX2 is ΔH∘f=−681 kJ/mol. The enthalpy of sublimation of M is ΔHsub=145 kJ/mol. The first and second ionization energies of M are IE1=607 kJ/mol and IE2=1444 kJ/mol. The electron affinity of X is ΔHEA=−315 kJ/mol. The bond energy of X2 is BE=247 kJ/mol. Determine the lattice energy of MX2. I've been stuck on this question...
The common oxidation number for an alkaline earth metal is +2. Using the Kapustinskii equation and Born-Haber cycles, show that CaCl is an exothermic compound, where CaCl may have NaCl structure. Use a suitable analogy to estimate an ionic radius for Ca. Use a radius for Ca. (rg and rca is 1.38 and 1.00 A, respectively.) suitable analogy to estimate an ionic 0.345 1.21 2 Z,n U To where En is the # of ions in the empirical formula, the...
Consider the following information. The lattice energy of NaCl is ΔH lattice=−788 kJ/mol The enthalpy of sublimation of Na is ΔHsub=107.5 kJ/mol The first ionization energy of Na is IE1=496 kJ/mol. The electron affinity of Cl is ΔHEA=−349 kJ/mol. The bond energy of Cl2 is BE=243 kJ/mol. Determine the enthalpy of formation, ΔHf, for NaCl(s). ΔHf= kJ/mol
1. Using the Born-Landé equation and the Kapustinskii equation, calculate the lattice enthalpy of cesium chloride. Cesium: 181 and Chloride: 167 2. Construct a Born-Haber cycle to calculate the first ionization energy for cesium. (should you use the results from the Born-Landé or the Kapustinskii equation). 3. 3. Calculate the lattice energy of MgF2 (Born Haber). Use the Kapustinskii Equation to calculate the radius of the Mg2+ ion. Hint – you will need to solve a quadratic (set ro =...
Estimate the lattice energy, ?U, for NaF if the ionic radii for K+ and F– are 138.0 pm and 133.0 pm, respectively. Use the Kapustinskii equation.
Consider the following information. • The lattice energy of NaCl is AHlattice = –788 kJ/mol. • The enthalpy of sublimation of Na is AHsub = 107.5 kJ/mol. • The first ionization energy of Na is IE1 = 496 kJ/mol. • The electron affinity of Cl is AHEA = -349 kJ/mol. • The bond energy of Cl, is BE = 243 kJ/mol. Determine the enthalpy of formation, AHf, for NaCl(s). AH= kJ/mol
1.2. Consider a hypothetical ionic compound AB (comprised of At and B ions). Given the following enthalpy data and using a Born-Haber cycle calculation, predict AHlattice in kJ mol1. AB (s) A,H = -422 kJ mol-1 A (s) B (s) A (g) AH = 105 kJ mol1 A (s) B (g) A,H = 109 kJ mol-1 B (s) First ionization energy of A (gas phase) = 530 kJ mol1 -379 kJ mol-1 Electron affinity of B (taking into account it's...
Consider an ionic compound, MX2 composed of generic metal M and generic, gaseous halogen ?. The enthalpy of formation of MX2 is 사4°-_653 kJ/mol. The enthalpy of sublimation of M is dHsb = 1 17 kJ/mol. The first and second ionization energies of M are IE1-711 kJ/mol and IEz 1.370 x10 kJ/mol. The electron affinity of X is AHEA-321 kJ/mol. (Refer to the Hint). The bond energy of X2 is BE 173 kJ/mol. Determine the lattice energy of MX2 Number...
Consider an ionic compound, MX,, composed of generic metal M and generic, gaseous halogen X. • The enthalpy of formation of MX, is AH; = -989 kJ/mol. • The enthalpy of sublimation of M is AH sub = 131 kJ/mol. • The first and second ionization energies of M are IE1 = 615 kJ/mol and IE2 = 1392 kJ/mol. • The electron affinity of X is AHEA = -303 kJ/mol. (Refer to the hint). • The bond energy of X,...
Consider an ionic compound, MX, composed of generic metal M and generic, gaseous halogen X. Determine the lattice energy of MX.? The enthalpy of formation of MX is ?Hf° = –599 kJ/mol. The enthalpy of sublimation of M is ?Hsub = 107 kJ/mol. The ionization energy of M is IE = 467 kJ/mol. The electron affinity of X is ?HEA = –341 kJ/mol. (Refer to the hint). The bond energy of X2 is BE = 167 kJ/mol.