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1 1. Calculate the relative populations of the v1 state to the ground vibrational state for lz at...
1000 diatomic molecules with vibrational state described by N molecules in the ground vibrational...
1000 diatomic molecules with vibrational state described by N molecules in the ground vibrational state O molecules in the lowest potential Total Energy Potential Energy state M molecules in an excited vibrational states P molecules in an excited potential energy states Schematic of Energy Eigenfunctions and the 1. Consider a sample of 1000 identically prepared diatomic molecules, each of which can be Potential Energy function of the Harmonic Oscillator described by the ground state of the Harmonic oscillator: Ψ-ψ。. If...
any help would be great thanks Calculate the proportion of molecules of iodine (L) in their ground, first and se...
any help would be great thanks
Calculate the proportion of molecules of iodine (L) in their ground, first and second excited vibrational states at 25°C. The vibrational, wavenumber is 214.6 cm Hint E-hc (Ans: Po-0.645, P1-0.229. and P2-0.081) At what temperature would the vw1 level of I have (a) half the population of the ground state, (b) the same population of the ground state? (Ans: (a) 445K (b) infinite) 001439m h 6.6261x10 .5 c* 2.9979x10 m.s k 1.3507 x 10...
4. Anharmonic potential (15 points) The adjacent figure shows the experimentally determined potential energy curve of the electronic ground state of"Br2, with a few of the vibrational levels. The...
4. Anharmonic potential (15 points) The adjacent figure shows the experimentally determined potential energy curve of the electronic ground state of"Br2, with a few of the vibrational levels. The vibrational transitions are reasonably well described by a harmonic oscillator model, but much more accurately by including a small anharmonic correction term: En/hcVe(n 1/2) - vexe(n + 1/2)2. From fits to experimental data, the values of the constants are 325.32 cm and exe 1.08 cm .5 10 15 (a) Calculate the...
Calculate the ratio of HBr molecules in the first excited vibrational state compared to the ground state at 800K. Remember that finding the probability of finding a molecule in a given state, i, is re...
Calculate the ratio of HBr molecules in the first excited vibrational state compared to the ground state at 800K. Remember that finding the probability of finding a molecule in a given state, i, is related to its energy, Ei, by the following equation: P(n) e^(-En/KT) You will need the following information to calculate the energy of the vibrational states: En = hv(n+1/2) for HBr v= 7.944*10^14s^-1 K=1.3807*10^-24J/K h=6.626*10^-34J*s
The vibrational frequency of a CO molecule is 6.51x10135-1. What frequency of light is needed to...
The vibrational frequency of a CO molecule is 6.51x10135-1. What frequency of light is needed to excite this molecule from the v=0 vibrational state to the v=1 vibrational state, if it is treated as a harmonic oscillator? Report your frequency as a wavenumber, in units of cm-1. Question 4 1 pts The following table lists the frequency of light absorbed by several different molecules in order to excite their vibrational energy. molecule õ(cm-1) HBr 2649 HCI 2991 NO 1904 In...
In the ro-vibrational model for spectra of diatomic molecules, the total rotational and vibrational energy for...
In the ro-vibrational model for spectra of diatomic molecules, the total rotational and vibrational energy for a given state is: Évj = ū(v + 3) + BJC +1) (Equation 1) where v is the vibrational quantum number and J is the rotational quantum number. Complete the following steps to create a model energy level diagram for a hypothetical diatomic molecule with ✓ = 2000 cm-1 and B = 1 cm-1. i) Draw a horizontal line to represent the ground vibrational...
= μ = 0.5 This problem deals with the vibrational motion of the H2 molecule (reduced mass- amu). The Hamiltonian for this system is: h2 d 1, e2ndxī + 2kx2. 5 pts] By direct substitution of the wa...
= μ = 0.5 This problem deals with the vibrational motion of the H2 molecule (reduced mass- amu). The Hamiltonian for this system is: h2 d 1, e2ndxī + 2kx2. 5 pts] By direct substitution of the wavefunction labelled by the quantum number v, Where k is a constant related to the bond strength. V.(x), in the Schrödinger Equation, show that the wavefunction Ψ(x) = Noe- )' where α = ( corresponds to the ground vibrational state of H2 having...
Quantum, 1D harmonic oscillator. Please answer in full. Thanks. Q3. The energy levels of the 1D harmonic oscillator are given by: En = (n +2)ha, n=0. 1, 2, 3, The CO molecule has a (reduced) mass of...
Quantum, 1D harmonic oscillator. Please answer in full.
Thanks.
Q3. The energy levels of the 1D harmonic oscillator are given by: En = (n +2)ha, n=0. 1, 2, 3, The CO molecule has a (reduced) mass of mco = 1.139 × 10-26 kg. Assuming a force constant of kco 1860 N/m, what is: a) The angular frequency, w, of the ground state CO bond vibration? b) The energy separation between the ground and first excited vibrational states? 7 marks] The...
3. (a) Consider a 1-dim harmonic oscillator in its ground state (0) of the unperturbed Hamiltonian at t--0o. Let a pert...
3. (a) Consider a 1-dim harmonic oscillator in its ground state (0) of the unperturbed Hamiltonian at t--0o. Let a perturbation Hi(t)--eEXe t2 (e, E and rare constants) be applied between - and too. What is the probability that the oscillator will be in the state n) (of the unperturbed oscillator) as t-> oo?(15%) (b) The bottom of an infinite well is changed to have the shape V(x)-ε sin® for 0Sxa. Calculate the energy shifts for all the excited states...
4. (20 points) Harmonic Oscillator The ground state wave function of a simple harmonic oscillator is...
4. (20 points) Harmonic Oscillator The ground state wave function of a simple harmonic oscillator is (a) = Ae-42", where a = (a) Using the normalization condition, obtain the constant A. (b) Find (c), (), and Az, using the result of A obtained in (a). Again, A.= V(32) - (2) (c) Find (p) and Ap. For the latter, you need to evaluate (p). Hint: For a harmonic oscillator, the time-averaged kinetic energy is equal to the time-averaged potential energy, and...
1000 diatomic molecules with vibrational state described by N molecules in the ground vibrational state O molecules in the lowest potential Total Energy Potential Energy state M molecules in an excited vibrational states P molecules in an excited potential energy states Schematic of Energy Eigenfunctions and the 1. Consider a sample of 1000 identically prepared diatomic molecules, each of which can be Potential Energy function of the Harmonic Oscillator described by the ground state of the Harmonic oscillator: Ψ-ψ。. If...
any help would be great thanks
Calculate the proportion of molecules of iodine (L) in their ground, first and second excited vibrational states at 25°C. The vibrational, wavenumber is 214.6 cm Hint E-hc (Ans: Po-0.645, P1-0.229. and P2-0.081) At what temperature would the vw1 level of I have (a) half the population of the ground state, (b) the same population of the ground state? (Ans: (a) 445K (b) infinite) 001439m h 6.6261x10 .5 c* 2.9979x10 m.s k 1.3507 x 10...
4. Anharmonic potential (15 points) The adjacent figure shows the experimentally determined potential energy curve of the electronic ground state of"Br2, with a few of the vibrational levels. The vibrational transitions are reasonably well described by a harmonic oscillator model, but much more accurately by including a small anharmonic correction term: En/hcVe(n 1/2) - vexe(n + 1/2)2. From fits to experimental data, the values of the constants are 325.32 cm and exe 1.08 cm .5 10 15 (a) Calculate the...
The vibrational frequency of a CO molecule is 6.51x10135-1. What frequency of light is needed to excite this molecule from the v=0 vibrational state to the v=1 vibrational state, if it is treated as a harmonic oscillator? Report your frequency as a wavenumber, in units of cm-1. Question 4 1 pts The following table lists the frequency of light absorbed by several different molecules in order to excite their vibrational energy. molecule õ(cm-1) HBr 2649 HCI 2991 NO 1904 In...
In the ro-vibrational model for spectra of diatomic molecules, the total rotational and vibrational energy for a given state is: Évj = ū(v + 3) + BJC +1) (Equation 1) where v is the vibrational quantum number and J is the rotational quantum number. Complete the following steps to create a model energy level diagram for a hypothetical diatomic molecule with ✓ = 2000 cm-1 and B = 1 cm-1. i) Draw a horizontal line to represent the ground vibrational...
= μ = 0.5 This problem deals with the vibrational motion of the H2 molecule (reduced mass- amu). The Hamiltonian for this system is: h2 d 1, e2ndxī + 2kx2. 5 pts] By direct substitution of the wavefunction labelled by the quantum number v, Where k is a constant related to the bond strength. V.(x), in the Schrödinger Equation, show that the wavefunction Ψ(x) = Noe- )' where α = ( corresponds to the ground vibrational state of H2 having...
Quantum, 1D harmonic oscillator. Please answer in full.
Thanks.
Q3. The energy levels of the 1D harmonic oscillator are given by: En = (n +2)ha, n=0. 1, 2, 3, The CO molecule has a (reduced) mass of mco = 1.139 × 10-26 kg. Assuming a force constant of kco 1860 N/m, what is: a) The angular frequency, w, of the ground state CO bond vibration? b) The energy separation between the ground and first excited vibrational states? 7 marks] The...
3. (a) Consider a 1-dim harmonic oscillator in its ground state (0) of the unperturbed Hamiltonian at t--0o. Let a perturbation Hi(t)--eEXe t2 (e, E and rare constants) be applied between - and too. What is the probability that the oscillator will be in the state n) (of the unperturbed oscillator) as t-> oo?(15%) (b) The bottom of an infinite well is changed to have the shape V(x)-ε sin® for 0Sxa. Calculate the energy shifts for all the excited states...
4. (20 points) Harmonic Oscillator The ground state wave function of a simple harmonic oscillator is (a) = Ae-42", where a = (a) Using the normalization condition, obtain the constant A. (b) Find (c), (), and Az, using the result of A obtained in (a). Again, A.= V(32) - (2) (c) Find (p) and Ap. For the latter, you need to evaluate (p). Hint: For a harmonic oscillator, the time-averaged kinetic energy is equal to the time-averaged potential energy, and...
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