Homework Answers
Kmno4 is a strong oxidizing agent and oxidize the alkene to Carboxylic acid.
LiAlH4 reduce the amide into amine.
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KMnO PBr, ether NaH +NaC +HB CH,Ci DMSO NH, ether 2 NH(CH) amide here alcohol here LAIH H,o ether...
Fill in the blanks (0.25 10 2.5 pts) KMnO PBr NaH ether + NaCl +HBr CH,ci...
Fill in the blanks (0.25 10 2.5 pts) KMnO PBr NaH ether + NaCl +HBr CH,ci DMSO NH 2 NH(CHsh ether amide here alcohol here LiAIH +(CH) NH Br ether H20
Give the missing reagent(s). Matching H2SO., H30 Cl2 1) Br, H;O 2) NaH KMnO Cold, Dilute,Basic...
Give the missing reagent(s). Matching H2SO., H30 Cl2 1) Br, H;O 2) NaH KMnO Cold, Dilute,Basic HCI 1) BH THE 2) H2O2, OH 1) Hg(OAc), H:0 2) NaBH, OH 1) Os 2) (CH3)2S H20, H SO. mCPBA 1) mCPBA 2) H30 Na. 1) OsO. 2) NaHSO; Liquid NH; 1) mCPBA 2) H30, OH Lindlar's Catalyst
H,Cro SOCI: H,0 Pyridine PCC CH,CI, HIO HR Peroxide 2. H,0,HCI NES CH- - HN CH,I,...
H,Cro SOCI: H,0 Pyridine PCC CH,CI, HIO HR Peroxide 2. H,0,HCI NES CH- - HN CH,I, Zn(Cu) ether 1.0, 2. (CH) KCN HCN 1.00 2. NaHSO, H,0 HO 2. HCI, H20 H.SO 1. BH. THE 2. H,O, NaOH 1. HgOAC), 2,0 2. NaBH, HUNCH, 1. NBH 2. H.O
For each reacuon ere s only as an aid for you. 1) KOH, H-O, heat Diethyl malonate B 1) Ph3P, ether 2) nBuLi, ether CIH1...
For each reacuon ere s only as an aid for you. 1) KOH, H-O, heat Diethyl malonate B 1) Ph3P, ether 2) nBuLi, ether CIH1204 2) H, H2O, heat C1SH2406 CHH1202 NaOEt, EtOH Br OCH2CH3 3) PHCHO NH/heat Note: The C-13 NMRS for Structures C, D, and E each show 7 resonances LIAIH D E C1HNO ether C1H1SN Br 1) SOCI2, pyridine F 2) CH3OH 1) CH2COCI,AICI3 1) Mg(s), Et20 H 2) diisopropyl amine, pH 4.5, NaBH3CN 2) CO2 (s)...
I. BALANCE by CHANGE in OXIDATION NUMBER CH o co, H,O 1. (NH),Cr,O, 2. Cr,o,+ H,O+...
I. BALANCE by CHANGE in OXIDATION NUMBER CH o co, H,O 1. (NH),Cr,O, 2. Cr,o,+ H,O+ N co P,O, H0 H,PO, C> 3. Ni(NO,+ S NO H,O NiS HNO,- 4. MnSO,+ Na,SO, + KSO,+ C+ H,O KMnO,+ NaCl H,SO 5. 79
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH,...
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH, CH,CH2CH Predict the major products of the following reactions, including stereochemistry where appropriate. (a) (R)-2-butanol + TsCl in pyridine c) cyclooctanol + CrO3/H2SO4 (e) cyclopentylmethanol + Na2Cr 01/H2SO4 (g) n-butanol + HBr (i) potassium t-butoxide + methyl iodide (k) cyclopentanol + H2SO4/heat (m) sodium ethoxide +1-bromobutane (b) (S)-2-butyl tosylate +NaBr (d) cyclopentylmethanol + CrOs pyridine HC cyclopentanol + HCI/ZnCl2 (h) cyclooctylmethanol + CH3CH2MgBr (G)...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
Please write neatly. 3. Show the products formed in the tollowing reactions draw two enols 1) Mg. Et O 2) CO2 3) H:O NHz Jo .OTo. 쁘. pyridne CI NH Ci CI 0 SOCl OH heat NH 1) CH3MgBr excess CH, C...
Please write neatly.
3. Show the products formed in the tollowing reactions draw two enols 1) Mg. Et O 2) CO2 3) H:O NHz Jo .OTo. 쁘. pyridne CI NH Ci CI 0 SOCl OH heat NH 1) CH3MgBr excess CH, CH, -OCH,C 2) H2O COOMe LIAIH OH Ci 0
3. Show the products formed in the tollowing reactions draw two enols 1) Mg. Et O 2) CO2 3) H:O NHz Jo .OTo. 쁘. pyridne CI NH Ci CI
0...
12. Which of the following molecules represent ci-2. Hexene? A CHE HOCH,CH.CH CH CH,CH.CH -H CH,CH,...
12. Which of the following molecules represent ci-2. Hexene? A CHE HOCH,CH.CH CH CH,CH.CH -H CH,CH, D. CH3 CH, "CHCH 13) What is the major organic product of the following reaction? CH:CH-CH2 + H20 H 14) The angle between the bonds in CH, is approximately __ a) 104.5° b) 109. 5° C ) 90° d) 120 15) Which of the following organic families is present in the molecule provided below? CH, CH2=CH2-CH a) ether b) alkane c ) alkene d)...
practice complely the follow, + NaOH following (Fill in the Blanks (ose wnds carboxylic Acid +...
practice
complely the follow, + NaOH following (Fill in the Blanks (ose wnds carboxylic Acid + Amine water carboxylic Aad & Alcohol Carboxylic Acid water Esten + H₂O + tre hydrolysis? Amide + H₂O titre hydedlysis Show the reagent / reagents needed to make the following molecolar conversions. Show reagent (s) to the right. Seach=40 HC=CH₂ HC-CH₃ 4 ة= SH please note: the is an aromated ring. It does not atlect the chemistry Hocao 0 ÖzçēH (oxidation? bacco in there...
Fill in the blanks (0.25 10 2.5 pts) KMnO PBr NaH ether + NaCl +HBr CH,ci DMSO NH 2 NH(CHsh ether amide here alcohol here LiAIH +(CH) NH Br ether H20
Give the missing reagent(s). Matching H2SO., H30 Cl2 1) Br, H;O 2) NaH KMnO Cold, Dilute,Basic HCI 1) BH THE 2) H2O2, OH 1) Hg(OAc), H:0 2) NaBH, OH 1) Os 2) (CH3)2S H20, H SO. mCPBA 1) mCPBA 2) H30 Na. 1) OsO. 2) NaHSO; Liquid NH; 1) mCPBA 2) H30, OH Lindlar's Catalyst
H,Cro SOCI: H,0 Pyridine PCC CH,CI, HIO HR Peroxide 2. H,0,HCI NES CH- - HN CH,I, Zn(Cu) ether 1.0, 2. (CH) KCN HCN 1.00 2. NaHSO, H,0 HO 2. HCI, H20 H.SO 1. BH. THE 2. H,O, NaOH 1. HgOAC), 2,0 2. NaBH, HUNCH, 1. NBH 2. H.O
For each reacuon ere s only as an aid for you. 1) KOH, H-O, heat Diethyl malonate B 1) Ph3P, ether 2) nBuLi, ether CIH1204 2) H, H2O, heat C1SH2406 CHH1202 NaOEt, EtOH Br OCH2CH3 3) PHCHO NH/heat Note: The C-13 NMRS for Structures C, D, and E each show 7 resonances LIAIH D E C1HNO ether C1H1SN Br 1) SOCI2, pyridine F 2) CH3OH 1) CH2COCI,AICI3 1) Mg(s), Et20 H 2) diisopropyl amine, pH 4.5, NaBH3CN 2) CO2 (s)...
I. BALANCE by CHANGE in OXIDATION NUMBER CH o co, H,O 1. (NH),Cr,O, 2. Cr,o,+ H,O+ N co P,O, H0 H,PO, C> 3. Ni(NO,+ S NO H,O NiS HNO,- 4. MnSO,+ Na,SO, + KSO,+ C+ H,O KMnO,+ NaCl H,SO 5. 79
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH, CH,CH2CH Predict the major products of the following reactions, including stereochemistry where appropriate. (a) (R)-2-butanol + TsCl in pyridine c) cyclooctanol + CrO3/H2SO4 (e) cyclopentylmethanol + Na2Cr 01/H2SO4 (g) n-butanol + HBr (i) potassium t-butoxide + methyl iodide (k) cyclopentanol + H2SO4/heat (m) sodium ethoxide +1-bromobutane (b) (S)-2-butyl tosylate +NaBr (d) cyclopentylmethanol + CrOs pyridine HC cyclopentanol + HCI/ZnCl2 (h) cyclooctylmethanol + CH3CH2MgBr (G)...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
Please write neatly.
3. Show the products formed in the tollowing reactions draw two enols 1) Mg. Et O 2) CO2 3) H:O NHz Jo .OTo. 쁘. pyridne CI NH Ci CI 0 SOCl OH heat NH 1) CH3MgBr excess CH, CH, -OCH,C 2) H2O COOMe LIAIH OH Ci 0
3. Show the products formed in the tollowing reactions draw two enols 1) Mg. Et O 2) CO2 3) H:O NHz Jo .OTo. 쁘. pyridne CI NH Ci CI
0...
12. Which of the following molecules represent ci-2. Hexene? A CHE HOCH,CH.CH CH CH,CH.CH -H CH,CH, D. CH3 CH, "CHCH 13) What is the major organic product of the following reaction? CH:CH-CH2 + H20 H 14) The angle between the bonds in CH, is approximately __ a) 104.5° b) 109. 5° C ) 90° d) 120 15) Which of the following organic families is present in the molecule provided below? CH, CH2=CH2-CH a) ether b) alkane c ) alkene d)...
practice
complely the follow, + NaOH following (Fill in the Blanks (ose wnds carboxylic Acid + Amine water carboxylic Aad & Alcohol Carboxylic Acid water Esten + H₂O + tre hydrolysis? Amide + H₂O titre hydedlysis Show the reagent / reagents needed to make the following molecolar conversions. Show reagent (s) to the right. Seach=40 HC=CH₂ HC-CH₃ 4 ة= SH please note: the is an aromated ring. It does not atlect the chemistry Hocao 0 ÖzçēH (oxidation? bacco in there...
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