For each set of compounds shown below, rank them in order of the 'H NMR chemical shift of their o...
NMR spectra for each of the compounds with a chemical shift, multiplicity and H. O.
1. Rank the compounds in each group, groups l- IV, (1 - highest Rf value, 3-lowest Rf value) on a TLC plate run using a 1:1 hexanes:ethyl acetate as an eluent. (3 pts) Group l: OH Group ll: HN HO Group IlI: NH2 NH2 NO2 NO2 Group IV: он
11.4 Pre-lab questions 1) Predict the 'H-NMR chemical shift (ppm) using empirical parameter (Curphy-Morrison) values, coupling pattern, and approximate J value (Hz) of each of the 'H-atoms present in an possible mono-nitrated bromobenzenes as shown in the table below. Use the H-atom labeling key provided on page 11-9. (3 pts) Ho HV Hi HY NOZ HO HY NO2 shift, coupling pattern, and J value O NYH Hm shift, coupling pattern, and J value shift, coupling pattern, and J value Hh...
Draw the expected H NMR spectrum for each molecule. Pay attention to the chemical shift and splitting. Mark the integration of each peak. Then assign each peak in the NMR to hydrogen atoms in the structure. HyC 0 ppm 192 t2 .3 +5 o t6 O=C +7 C=O +8
Which of the compounds shown below are chiral? (choose all correct) ОН o ОН E Which of the compounds shown below is/are chiral? (choose all correct answers) O For determining whether a stereogenic center is Ror S. the substituents need to be ranked. Rank the following substituents from high to low, entering a 1,2,3, or 4 next to each structure, with 1 for highest priority ranking and 4 for lowest priority ranking. 0-6 -C-H -CH_Br -CH₂OH -c-oh Which of the...
HETNTY TImm 3) Use empirical (Curphy-Morrison-type) parameters to predict the 'H-NMR chemical shift values of each set of 'H-atoms of the mono-acylated regioisomers expected for this reaction. (3 pts) :0
1. please check what is wrong. Thank you! Determine the product formed when each compound is treated with Br2 and FeBr3. Drag the atom labels to their appropriate positions. CN Atom labels H H Br Br2 A. FeBr Br H OH OH Br Br. Br2 FeBr3 H H Br Br H Br2 FeBr H1 H Reset T Rank the compounds in each group in order of decreasing reactivity in electrophilic aromatic substitution. CI Decreasing reactivity Rank the compounds in each...
The H-NMR spectrum of an unknown compound (formula CaHgO2) is shown below. Draw the structure of the unknown compound. Question 5 4 1 6 5 8 10 11 Ppm The 13C-NMR spectrum of an unknown compound (formula CgH180) is shown below. Its 1H-NMR spectrum only shows one singlet at 1.2 ppm. Draw the structure of this unknown compound. uestion 2 220 200 160 140 120 PPM 100 80 240 180 60 40 20 Create OscerSketch Answer 2 What would be...
(6 pts total: 2 pts each) Proteins that catalyze chemical reactions in living systems are called enzymes. The basic building blocks of proteins are called amino acids and have the general structure pictured below, left, where R is a substituent containing one of many organic functional groups. Some representative examples of amino acids found in nature are pictured here as well (R groups only) O . CH, HO-C-H H-C-H HẠC-C-CH, CH,SH HNT-CO,H Cysteine Valine Threonine Aspartic Acid An Amino Acid...
help with identifiying each unknown in extraction and washing experiment. the ir spectra are given below, along with data, and the lab sheet is attached. Neutral Solid Primary amine (Aniline) 3403cm - NE presence Transmittance 60 3258cm 1 streren NOUD Streich 50 Ctretcher strator NH2 aromatto 11 NO2 aring 2-nitroaniline K LILI 3600 3200 2800 2400 2000 1800 1600 Wavenumber cm-1 1400 1200 1000 800 600 Basic Solid primary amine Transmittance I NH2 Stretch p-acetvianiline 70 60 CS HG NO...