For each complex in the Monsanto Acetic Acid Process, indicate the following:
1. Name of step
2. oxidation state of the metal
3. d electron count
4. total electron count
5. turnover number
6. turnover frequency
7. geometry
8. coordination number
Homework Answers
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For each complex in the Monsanto Acetic Acid Process, indicate the following: 1. Name of step 2. ...
2. Indicate i. the metal oxidation state, ii. d-electron count, and iii. coordination number (CN) for...
2. Indicate i. the metal oxidation state, ii. d-electron count, and iii. coordination number (CN) for the following complex (12 Points). a. Anti-cancer drug b. [Fe S4(SR)] SR Fe COS i. ii. ii. iii. iii. 3. Draw the metal coordination structure of carbonic anhydrase enzyme. Clearly show the 3-D geometry round the metal center. (6 Points)
In detail, write out the Monsanto acetic acid catalytic cycle using (RhL;(CO)2] as the precatalyst Label...
In detail, write out the Monsanto acetic acid catalytic cycle using (RhL;(CO)2] as the precatalyst Label all steps in the cycle and give the oxidation state of the metal in each intermediate. Identify the rate-determining step of the catalytic cycle Alkyl ligands are typically very strong anionic 6-donors with no T-acceptor ability One of the most common reactions of alkyls is the B-hydride elimination reaction Describe the B-hydride elimination reaction in general terms. Illustrate your answer with relevant drawings using...
2. Indicate i. the metal oxidation state, ii. d-electron count, and iii. coordination number (CN) for...
2. Indicate i. the metal oxidation state, ii. d-electron count, and iii. coordination number (CN) for the following complex (12 Points). a. Anti-cancer drug b. [Fe4S4(SR)4]2- SR S > Fe Cmos i. i. ii. ii. iii. 5. Draw the metal coordination structure of carbonic anhydrase enzyme. Clearly show the ? geomet 21
ach of the following processes? Indicate As (a) A liquid freezes,-L (b) A liquid boils. (c)...
ach of the following processes? Indicate As (a) A liquid freezes,-L (b) A liquid boils. (c) A vapor is converted to a solid.O (d) A solid sublimes. 7. (1 pt. each) In Ks[Fe(C,Oa)l complex a) How many number of possible donor atoms are there in the coordination complex ion? b) What is the coordination number for the coordination complex ion? c) What is the oxidation number on the metal, Fe2 + (1 pt. each) Write the complex ion formula for...
number 2! 1 Name three physiological properties of aspirin. Reduces inflammation ACID 1 2 pain Fever...
number 2!
1 Name three physiological properties of aspirin. Reduces inflammation ACID 1 2 pain Fever 3 2 Naproxen is a potent painkiller found in the drug Aleve. Based on the structure of naproxen, would you expect its analgesic properties to result from the same chemical reaction with the human body that makes aspirin a good pain reliever? Explain your answer. CH3 H H - acting он to relieve paiN H3CO H - C 1 H H naproxen 3 A...
CH3 CH3 1. Hg(OAC), H20 2. NaBH НО, І CH3 CH, Hoc H₃C/ Acid-catalyzed addition of...
CH3 CH3 1. Hg(OAC), H20 2. NaBH НО, І CH3 CH, Hoc H₃C/ Acid-catalyzed addition of water to an alkene yields an alcohol with Markovnikov regiochemistry. The electrophilic H adds to the sp carbon with the most hydrogens to yield the most stable carbocation intermediate, which then adds water to give the product alcohol. Because a carbocation intermediate is formed, rearrangements can occur prior to the addition of water. To avoid the possibility of rearrangement and still give a Markovnikov...
QUESTION 1 Match the 1-3 word answers for the following statements related to fatty acid oxidation...
QUESTION 1 Match the 1-3 word answers for the following statements related to fatty acid oxidation and fatty acid synthesis. In animal cells, fatty acid synthesis carried A. Cytosol out in the B. Mitochondrial matrix. The site of B-oxidation in the cell is C. Malonyl-CoA Intermediate in fatty acid synthesis that D. Complex I inhibits carnitine acyltransferase I, thus regulating fatty acid oxidation. E. Carnitine in the third step of B-0&1&atiov, electrons are NADPH transferred to NAD+; NADH then donates...
Determine the enantiomeric excess (1) and indicate which configuration (2), S or R, is in excess....
Determine the enantiomeric excess (1) and indicate which configuration (2), S or R, is in excess. If R-3-bromo-2- methylhexane is -80 degrees, would a polarimetry reading of the mixture in this problem rotate light (3) clockwise (CW) or counterclockwise (CC) (8) Br Br 15% 85% (this question is worth 9 points, not 8 as stated in the picture) 1. determine enantiomeric excess (your answer should be a number) 2. determine whether excess is S or R. 3. Does the mixture...
please write legible 1. Identify each of the following reactions as a precipitation reaction, an acid-base...
please write legible
1. Identify each of the following reactions as a precipitation reaction, an acid-base reaction, or as a redox reaction + a. Pb(NO3)2 (aq) + 2 HCl(aq) PbCl (s) + 2 HNO, (aq) b. 2 Hxe + O2 + 2 H2O c. HNO, (aq) + KOH(aq) KNO, (aq) + H20 (1) d. Zna + 2HCl(a) - ZnClaraq) + Halle e. Ba?'(aq) + 2 Br(aq) + 2 Na(aq) + SO/"(aq) BaSO. (s) + 2 Na'(aq) + 2 Br" (aq)...
How to solve alkene and alkyne reactions - Merdanym i Act antalyzod Hrdian ca Come Lazarmistry...
How to solve alkene and alkyne reactions
- Merdanym i Act antalyzod Hrdian ca Come Lazarmistry I V WORKSHOP #9 Alkenes, Alkynes, Reactions 1. Give a reasonable mechanism for the following reaction. Clearly show intermediates and show the movement of electron pairs with curved arrows. all сна H20. (H2SO4) H₃C CH₂ нас он H3CX сна 2. The addition of HBr to 2-methylpropene can, in principle, give either 1-bromo-2- methylpropane or 2-bromo-2-methylpropane. In reality, only the latter is formed. Show mechanisms...
2. Indicate i. the metal oxidation state, ii. d-electron count, and iii. coordination number (CN) for the following complex (12 Points). a. Anti-cancer drug b. [Fe S4(SR)] SR Fe COS i. ii. ii. iii. iii. 3. Draw the metal coordination structure of carbonic anhydrase enzyme. Clearly show the 3-D geometry round the metal center. (6 Points)
In detail, write out the Monsanto acetic acid catalytic cycle using (RhL;(CO)2] as the precatalyst Label all steps in the cycle and give the oxidation state of the metal in each intermediate. Identify the rate-determining step of the catalytic cycle Alkyl ligands are typically very strong anionic 6-donors with no T-acceptor ability One of the most common reactions of alkyls is the B-hydride elimination reaction Describe the B-hydride elimination reaction in general terms. Illustrate your answer with relevant drawings using...
2. Indicate i. the metal oxidation state, ii. d-electron count, and iii. coordination number (CN) for the following complex (12 Points). a. Anti-cancer drug b. [Fe4S4(SR)4]2- SR S > Fe Cmos i. i. ii. ii. iii. 5. Draw the metal coordination structure of carbonic anhydrase enzyme. Clearly show the ? geomet 21
ach of the following processes? Indicate As (a) A liquid freezes,-L (b) A liquid boils. (c) A vapor is converted to a solid.O (d) A solid sublimes. 7. (1 pt. each) In Ks[Fe(C,Oa)l complex a) How many number of possible donor atoms are there in the coordination complex ion? b) What is the coordination number for the coordination complex ion? c) What is the oxidation number on the metal, Fe2 + (1 pt. each) Write the complex ion formula for...
number 2!
1 Name three physiological properties of aspirin. Reduces inflammation ACID 1 2 pain Fever 3 2 Naproxen is a potent painkiller found in the drug Aleve. Based on the structure of naproxen, would you expect its analgesic properties to result from the same chemical reaction with the human body that makes aspirin a good pain reliever? Explain your answer. CH3 H H - acting он to relieve paiN H3CO H - C 1 H H naproxen 3 A...
CH3 CH3 1. Hg(OAC), H20 2. NaBH НО, І CH3 CH, Hoc H₃C/ Acid-catalyzed addition of water to an alkene yields an alcohol with Markovnikov regiochemistry. The electrophilic H adds to the sp carbon with the most hydrogens to yield the most stable carbocation intermediate, which then adds water to give the product alcohol. Because a carbocation intermediate is formed, rearrangements can occur prior to the addition of water. To avoid the possibility of rearrangement and still give a Markovnikov...
QUESTION 1 Match the 1-3 word answers for the following statements related to fatty acid oxidation and fatty acid synthesis. In animal cells, fatty acid synthesis carried A. Cytosol out in the B. Mitochondrial matrix. The site of B-oxidation in the cell is C. Malonyl-CoA Intermediate in fatty acid synthesis that D. Complex I inhibits carnitine acyltransferase I, thus regulating fatty acid oxidation. E. Carnitine in the third step of B-0&1&atiov, electrons are NADPH transferred to NAD+; NADH then donates...
Determine the enantiomeric excess (1) and indicate which configuration (2), S or R, is in excess. If R-3-bromo-2- methylhexane is -80 degrees, would a polarimetry reading of the mixture in this problem rotate light (3) clockwise (CW) or counterclockwise (CC) (8) Br Br 15% 85% (this question is worth 9 points, not 8 as stated in the picture) 1. determine enantiomeric excess (your answer should be a number) 2. determine whether excess is S or R. 3. Does the mixture...
please write legible
1. Identify each of the following reactions as a precipitation reaction, an acid-base reaction, or as a redox reaction + a. Pb(NO3)2 (aq) + 2 HCl(aq) PbCl (s) + 2 HNO, (aq) b. 2 Hxe + O2 + 2 H2O c. HNO, (aq) + KOH(aq) KNO, (aq) + H20 (1) d. Zna + 2HCl(a) - ZnClaraq) + Halle e. Ba?'(aq) + 2 Br(aq) + 2 Na(aq) + SO/"(aq) BaSO. (s) + 2 Na'(aq) + 2 Br" (aq)...
How to solve alkene and alkyne reactions
- Merdanym i Act antalyzod Hrdian ca Come Lazarmistry I V WORKSHOP #9 Alkenes, Alkynes, Reactions 1. Give a reasonable mechanism for the following reaction. Clearly show intermediates and show the movement of electron pairs with curved arrows. all сна H20. (H2SO4) H₃C CH₂ нас он H3CX сна 2. The addition of HBr to 2-methylpropene can, in principle, give either 1-bromo-2- methylpropane or 2-bromo-2-methylpropane. In reality, only the latter is formed. Show mechanisms...
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