Pohynuclear Aromatic Hyocarbos 19an LEM 15-4 the bay region theory, would you expect naphthalene ...
On the basis of kinetic theory, would you expect the rate of diffusion in a liquid to increase or decrease as the temperature is increased? Explain by selecting all true statements. 1. The average distance traveled in a unit of time would decrease. 2. The average distance between collisions would stay about the same. 3. The average distance traveled in a unit of time would increase. 4.The average speed of the molecules would stay the same. 5. The average speed...
Question 5 [time = 15 minutes] (a) How many lines would you expect for the EPR spectra of radicals A-C? H OCD3 H OCH3 Нас Hас OCD3 CH2CH3 (b) One of the two diastereomers of 2,6-dimethylcyclohexyl benzylether shown below exhibits two doublets for the benzylic protons (geminal coupling) in the H NMR spectrum нн 2J Draw the isomer clearly showing the relative configuration of the stereocentres. (ii) Provide a brief explanation for this finding. (iii) What signal (s) would you...
Cyclobutadiene is an anti-aromatic molecule. What was your calculated HOMO-LUMO gap for cyclobutadiene? Would you expect this molecule to be paramagnetic or diamagnetic based on the calculated gap? The HOMO-LUMO gap I got using Webmo was 0.012 eV. 2. 11-cis-retinal plays a role in our vision. When an electron gets promoted it becomes easier to the cis-bond to rotate to the trans-isomer. What color light causes the promotion of an electron from the HOMO-LUMO for that molecule? 3. Pentacene has...
1. Which one of the following two compounds would you expect to have a higher solubility in liquid CO2. Explain your reasoning in a few sentences: 2. Explain why percent recovery is utilized in the CO2 extraction of Eugenol as opposed to a theoretical yield. Limit yourself to 1-3 sentences. 3. List 3 signals that should be observed in the IR spectrum of Eugenol (whose structure is shown to the right). 4. In your own words, explain the purpose of...
4. What product(s) would you expect from the reaction of 1,4-hexadiene with NBS? What is the structure of the most stable radical intermediate? (5 marks)
Assignment: CO2 extraction of Eugenol 1. Which one of the following two compounds would you expect to have a higher solubility in liquid CO2. Explain your reasoning in a few sentences: HO. HC I CH ON CH3 Capsaicin Caffeine 2. Explain why percent recovery is utilized in the CO2 extraction of Eugenol as opposed to a theoretical yield. Limit yourself to 1-3 sentences. H3CO 3. List 3 signals that should be observed in the IR spectrum of Eugenol (whose structure...
How many 1H-NMR signals would you expect for each of the two starting materials in the reaction shown below? Please draw the reaction product for the reaction shown below. What are the approximate chemical shifts for each of the hydrogen atoms in the molecule?
In a Word document, answer the questions below: 1. The chromophore of GFP is what gives off the bright light. In the structure shown below, circle 1 amide, 1 amine, 1 carboxylic acid, and 1 alcohol. CH E H HN CH 2. In the structure shown above, (a) how many amides are there? (b) amines? (c) carboxylic acids (d) and phenols? 3. Referring back to the Project from Module 3, what IR bands would you expect to be prominent in...
How many signals would you expect in the 1H NMR spectrum of the compound below (assume no signals overlap)? O 1 O2 3 4 O 5 What ratio of integral values would be expected for the peaks in the proton NMR spectrum of the compound shown below? O A 2:2:3 O B. 3:2:2:3 OC. 2:3 O D. 3:1:1 O E 3:4:3
Would you expect the dipeptide valylalanine to give a positive reaction with nitric acid solution? Why or why not? 3, Would you expect the dipeptide valylalani Why or why not? alanine to give a positive reaction with nitric acid solution? 4. In the chromatogram below, calculate an Re for each component of the mixture. Which componert is probably the more polar compound? Solvent front Origin From a book or Internet source, find the pl of the amino acid lysine. What...