a
Let the depth of the pond be & its radius be
i) The volume of the cylinder is
Given
We have
ii) Given that
Substituting for , we have
b) The cost C can be written in terms of r & d as
where k, d are some constants
i) from part a) we have
Substituting back in the cost
we have
For this to be extremal &
Hence means
since
ii) If &
We have
In (i) above we have seen
Hence
iii) In a part (ii) we had
Since , this means
From part b (ii) we calculated
Since
The extremal condition on the cost is satisfied withinn the given constraints, the cost is minimal within the constraints.
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21C.1(a) The reaction of propylxanthate ion in acetic acid buffer solutions has the mechanism A− +H+→P. Near 30 °C the rate constant is given by the empirical expression kr=(2.05×1013) e−(8681K)/T dm3mol−1 s−1. Evaluate the energy and entropy of activation at 30 °C. 21C.1(b) The reaction A− +H+→P has a rate constant given by the empirical expression kr=(6.92×1012)e−(5925K)/T dm3mol−1 s−1. Evaluate the energy and entropy of activation at 25 °C. Please explain why they calculated H=E-RT like that like why is...