1. Which of the compounds listed below would you expect to have the highest boiling point? They all have approximately the same molecular weight.) a. CH CH CH CH CH b. CH3CH CH C2OH d. Cl,CH:CH,CI...
4 1 Write these compounds in order of increasing boiling points. Identify a mechanistic step which does not occur in the reaction between excess of methylmagnesium iodide and ethyl acetate. :0: + CH3 - Mgi (A) HO HO OH no 1 2 3 (A) 1<2<3 (B) (B) 2<l<3 (D) 3<I<2 :0 (C) 2 <3 <1 CH-Mgl. (C) 2. Which one is the most acidic compound. (A) ОН (B) + CH3-Mgl (D) (C) (D) OH Identify one of the steps in...
6. Which of the following compounds will have higher boiling point? a)CH CH2CH2OH b)CH,CH2CH2CH.CH c)HOCH CH2OH 7. What is the difference between alkane, alkene and alkyne? 8. Which of the following compound can participate in hydrogen bonding? i. 2-propanol Acetic acid ii. The side chain of serine iv. The side chain of phenylalanine a. i and il b. i only c. Iiland ly d. and iv 9. Rotation around each C-C bond is not possible for which compound? a. Propanol-2...
1. Which of the compounds below is expected to undergo Sg2 reaction to the highest degree? ~ a 2! The following substrate was subjected to a series of nucleophilic reactions. Which of the reagents below would be expected to progress climination reaction to the highest degree? elimination a) H.O b) Toso c) CH,COO d) HO el I Which of the following solvents should be correctly called aprotic solvent? M. a) aqua b) DMHA c) DMA d) MAC c) McОН The...
І. 7. Indicate which compound of the ones listed below would be expected to have the highest boiling point. САз сенсіз С САз н с аlѕ аѕ Слс - Сн, си, 8. Draw the 2 chair conformations of cis-1,3 dimethylcyclohexane. Ina stable. Cyclohexane. Indicate which is the most 9. Which energy diagram below indicates a 1 step reaction that is exothermic? 10. Which carbocation below is the most stable? Ca CH₂2 .CHCH e the product or products that would be...
13. Assuming that molecular weights are comparable, which of the following compounds would you expect to be the highest boiling? a. aldehyde b. alkene c. ketone dd. alcohol 14. Predict the resultant compound class when an aldehyde is oxidized ? a. hemiketal b. alcohol cc. carboxylic acid d. no reaction 15. Hemiacetals are? a. produced on the oxidation of a carboxylic acid b. result of the reaction between an aldehyde and a ketone cc.composed from Ether and OH group d....
() 1. Which of the following alkyl holides would you expect to be most reactive in a unimolecular reaction? CH3 a) CsM , CH, CH, CH, Br b) CEHCH CH BY c) CH, CCH, Br d) CH, CH2 CH CHE сн. он сня Br e) CHICCHE CH3 (4). 2. What would you expect to be the chief organic product(s) when tert-butyl bromide reacts with sodium acetylide, i.e.. CH + - CH3-C-Br + Na CECH ? CH a) 1 b) II...
7. Which compound below best fits the following spectral data? 8. How many signals would you expect to see in the broadband decoupled C^13 spectra of the following compounds? 9. If a proton gave an NMR signal at 3.2 ppm on a MHz NMR, what would the chemical shift be of this proton (in ppm) if the sample was run in 400 MHz NMR? 7. Which compound below best fits the following spectral data? (6 points) H-1 NMR 0.9 ppm...
Which of the following compounds is more stable? or A B A They have same stability B Onto which of the numbered atoms in this structure can the negative charge be moved by resonance delocalization? 8 4 5 3 7 HC 2 co 1 2, 4, 6 only 1, 3, 5, 8 only 1, 3, 5 only 2, 4, 6, 7 only Which Newman projection represents the most stable conformation of the following compound when viewed down the 2-3 carbon-carbon...
(2) 22. Of the following, which has the highest boiling point? b) CH, CH, CH, CH CH. CH CH CH OCHCH, CH, CH, CH, CH, CH, OH (4) 18. (R)-(+)-Glyceraldehyde: H нонсон A: is levorotatory. B: rotates plane-polarized light in a counterclockwise direction. C: rotates plane-polarized light in a clockwise direction. D: is racemic. (10) 19. Assign R, S configurations to each indicated stereogenic center in the molecules below. OH HOH HOHC NH lol norepinephrine CHO FORE trans-cyclopentane-1,2-diol COOH +05...
1. Which of the following compounds gives the fastest Syl reaction? Br 1 Br a. 1 d. 4 c. 3 b.2 2. What is the product of the following reaction? HBr Br Br Br OH d. 4 a. 1 3. Which compound would be the major elimination product of the following reaction? NaOCH.CH ethanol a. 1 b. 2 c. 3 d. 4 4. Which of the following would you expect to have the lowest boiling point? HO -OH 3 4...