KOIL E1OH Br H, CHi O LLiAIH 2 H,O H,C CH,CH-CHCH.CCH-CHi. CH,CH.OH- CH; HOCH-CH-CH-OH- CH,CH CHCH CCH CH CH, OH CH,CHCH,CH CH (acid catalyst) Clz HCl KOIL E1OH Br H, CHi O LLiAIH 2 H,O H,C...
(1) HCOAc),,H,O (2) N.BH, (1) BH, THE (2) H,02, OH (CH-CH),Cuti + CH,CH,CH-CHCH, Br
Provide the product for the following reaction І. Br HOCH,CH,OH Mg/ether H2SO, Н,0° 2. H,0 но он ОН он IV он у Predict the product of the following synthesis. 1. Br2, H20 2. NaOH, HO 3. CH2OH, H+ OCH, н,со OCH, A B с OCH OCH OCH, D E Predict the product for the following reaction. OH Acid Catalyst + 25 °C O А D с B
8. Is the following sequence of steps an appropriate synthesis for ibuprofen? Yes or No CHCH CH,CH3 HOCH CH OH (CH)2CHCc на AIClh CH CH3 Br -CHCH HOOC-CHCH3 HOOC-CHCH3 1.Mg, ether NES H2/Pd 3. Ho* 8. Is the following sequence of steps an appropriate synthesis for ibuprofen? Yes or No CHCH CH,CH3 HOCH CH OH (CH)2CHCc на AIClh CH CH3 Br -CHCH HOOC-CHCH3 HOOC-CHCH3 1.Mg, ether NES H2/Pd 3. Ho*
2) Name the following using cis/trans or E/Z nomenclature when necessary. O CH,Br =C CH HOCH CH CH C1 СІН, CH,CH CH CH CH CH3 C=C HAC CHCH,CI
predict the products of the following reactions 0 () CH,CH CCH,-C-OCH, NocCH (2) CH (3) Ho .heat (I) NaOCH2CH (2) H,O', heat (b) CH,-C-CH-C-OCH,CH,+ CH, (1) LDA -OH (c) Ph CH, () CH,CH,CH,Br (1) H2C-CH CH,Br (2) H0* OCH, NaOCH Ph (2) CH,CH,CH2CH2Br (g) product from part (f) (decarboxylation) 0 () CH,CH CCH,-C-OCH, NocCH (2) CH (3) Ho .heat (I) NaOCH2CH (2) H,O', heat (b) CH,-C-CH-C-OCH,CH,+ CH, (1) LDA -OH (c) Ph CH, () CH,CH,CH,Br (1) H2C-CH CH,Br (2) H0*...
draw the mesocompound and plane of symmetry CH (2) H CH,CHCH CH,CHCH Br
age 7 19. The reaction of CH, CH, CCH, CH, with H,/Ni forms a. pentane. b. one particular chiral pentanol. c. an equimolecular mixture of two chiral pentanols . d. one achiral pentanol. e. no product. 20. The p-orbital of a methyl radical carbon, CH,, Contains how many electrons? a. 1 b. 2 e. 3 d. 4 e. 0 21. (2R, 35)-2,3-Dichlorobutane and (25, 3R) -2,3-dichlorobutane are: a. enantiomers b. diastereomers e. identical d. conformational isomers e. constitutional isomers 22....
What is the product of the following reactions? H HOCH Bra, H307 HO-C-H HO-C-H CH, OH b) H HO- CH 1. Ag, NH3, OH HO -C-H 2 H HOCH CH, OH c) H. H-C-OH 1. NaBH. HO-CH 2. H:0* H-C-OH CH2OH
f) Clz -Noz Fell Br g) FeBry 1) NaNO2, H2SO4 -NH₂ 2) H₂O, Cu₂o, Cu(NO3)2 NO₂ :) ON V HN CH₂ CNH CHC-0° CH₃ j) H₃C- -Br .:) KNH, NHz(us),- 33°C 2) H2O
1 produt why? Julci Na CCH CH₃OH Slow why? CHI AC/ Nooche CH₂OH 2 produds fast why? aus Prepare from methyl cyclohexane