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f) Clz -Noz Fell Br g) FeBry 1) NaNO2, H2SO4 -NH₂ 2) H₂O, Cu₂o, Cu(NO3)2 NO₂...
e. 4-HC-C6H4-NH-C(O)-CH3 + Cl2/H4C-COH ------> H30* f. 4-nitro-1-chlorobenzene + NaOH H2O g. Ph-CH2-CH2-CH2-CO2H + AICI: ------->...
e. 4-HC-C6H4-NH-C(O)-CH3 + Cl2/H4C-COH ------> H30* f. 4-nitro-1-chlorobenzene + NaOH H2O g. Ph-CH2-CH2-CH2-CO2H + AICI: -------> h. All trans-H2C=CH-CH=CH-OCH3 + H2C=CH-C(O)-H i. 1-bromo-3-chlorobenzene + HNO3/H2SO4 j. CsH5-CH=CH-CH3 + HBr/peroxides --------> H30* k. Ph-CH2-CH3 + KMnO./NaOH/A ----------> L. CoHs-CCl3 + Bry/FeBr ---------- H30* m. Ph-Br + KNH/-33 °C --------
KOIL E1OH Br H, CHi O LLiAIH 2 H,O H,C CH,CH-CHCH.CCH-CHi. CH,CH.OH- CH; HOCH-CH-CH-OH- CH,CH CHCH CCH CH CH, OH CH,CHCH,CH CH (acid catalyst) Clz HCl KOIL E1OH Br H, CHi O LLiAIH 2 H,O H,C...
KOIL E1OH Br H, CHi O LLiAIH 2 H,O H,C CH,CH-CHCH.CCH-CHi. CH,CH.OH- CH; HOCH-CH-CH-OH- CH,CH CHCH CCH CH CH, OH CH,CHCH,CH CH (acid catalyst) Clz HCl
KOIL E1OH Br H, CHi O LLiAIH 2 H,O H,C CH,CH-CHCH.CCH-CHi. CH,CH.OH- CH; HOCH-CH-CH-OH- CH,CH CHCH CCH CH CH, OH CH,CHCH,CH CH (acid catalyst) Clz HCl
E) V 57. Identify the best product for the reaction. NH2 1. NaNO2, HCI, O C 2. CuCN A) CHANH B) NH₂ CEN D) CH= H
E) V 57. Identify the best product for the reaction. NH2 1. NaNO2, HCI, O C 2. CuCN A) CHANH B) NH₂ CEN D) CH= H
10 dd.) Br XS NBS CCL, A C Br ee. S0₂H 1. fuming H2SO4 2. HNO/H2SO4...
10 dd.) Br XS NBS CCL, A C Br ee. S0₂H 1. fuming H2SO4 2. HNO/H2SO4 3. Zn(Hg). HCI, A u ff.) OH HO ,Ph 1. H.CrO lacetone 2. PrMgl/Et20 3. H2O* gg.) HO3S. NH2 SQ3H -NH2 SO, H2SO4 303H hh.) OEt -CH₂-OH 1. LiAlH./Et20/ -78 °C 2. H2O il.) Ph Ph 1. Li/Et, 2. Ph Co 3. H,0 Pn
hh.) OEt 1. LIAIHJE!,0/-78 °C 2. H,0 1. LIELO 2. Ph.CO 3.H30 Br 1. Mg/THF 2....
hh.) OEt 1. LIAIHJE!,0/-78 °C 2. H,0 1. LIELO 2. Ph.CO 3.H30 Br 1. Mg/THF 2. formaldehyde 3. NHCl(aq) kk.) 2 Na, EtOH, NH CH,BF mm.) SOH 2 Na, EtOH, NH, nn.) NOZ H2SO4(conc) HNO3(conc) NO 00.) 1. SO, H,SO 2. NaOH/KOHA 3. H,0*
o Mg2+ Br 1 M Ý H2SO4/H20 H,80,140 + H2O + Mg2+ Br HSO4 2. +...
o Mg2+ Br 1 M Ý H2SO4/H20 H,80,140 + H2O + Mg2+ Br HSO4 2. + NaOH NaOH Nal нон a = Proton transfer b= Lewis acid/base c= Radical chain substitution d = Electrophilic addition e=E1 Elimination f=E2 Elimination g=Syl Nucleophilic substitution h=SN2 Nucleophilic substitution Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. 2. 1 Low Hoo H2SO4 i Ho HO 130° NaOH...
Ochem 2 ch 22 Ch 22 Amines (100 pts) Chemistry 2320 p) H&NO3/H2SO 1) Fe, HCI...
Ochem 2 ch 22
Ch 22 Amines (100 pts) Chemistry 2320 p) H&NO3/H2SO 1) Fe, HCI 2) NaOH H2N 1) H2NOg/H,SOA CUCN 2) NaNO2 H2SO4 г) 1) NaNO2 H2SO4 1) H2NO3/H2SO4 2) Fe, HCI 2) HBF4 6. Provide the most efficient synthesis possible by matching the reagents to the reaction. Write the letter(s) over or adjacent to the corresponding reaction arrow. As many as three steps represented by each letter may be needed. Assume intermediate products are isolated and purified...
please write the steps needed to get this product. A NaBH4/H:0 S KMnO4 HNO3 H2SO4 K...
please write the steps needed to get this product.
A NaBH4/H:0 S KMnO4 HNO3 H2SO4 K HNO3 H2SO4 B LiAlH4/H:07 T CH3MgBr/H:0* U 1. LDA/ 2. CH Br C Dess-Martin L Nal D CrOz/H:07 M H3PO4 V NaCN E H/Pd N Bry/FeBr3 W NH 0 CH:COCI/AICI: X CH3NH2 P CH:CH-CT/AICI: Y SOCI: F SnCl/H30* 1. Hg(OAc)2, H2O/THF G 2. NaBHA HH2SO4, H2O, HgSO4 1. BH3, THF 2. H2O2, OH Q H3O+/H20 Z CH OH R KOH O CHICHI CH3CH CH:CH-C-OH...
RM-Q14 What is the product of the following reaction? o 1) КОН 2) Br N-H ?...
RM-Q14 What is the product of the following reaction? o 1) КОН 2) Br N-H ? 3) H,0 4) dilute NaOH CH, NH, A) B) C) D) Select an answer and submit. For keyboard navigation, use the up/down arrow keys to select an answer. a A) b B) с C) d D) RM-Q36 Identify the sequence of reactions that will accomplish the following transformation in high yield. 1) CI AICIS A) - 2) Br2, FeBry AICI: O B) 1) CI...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
e. 4-HC-C6H4-NH-C(O)-CH3 + Cl2/H4C-COH ------> H30* f. 4-nitro-1-chlorobenzene + NaOH H2O g. Ph-CH2-CH2-CH2-CO2H + AICI: -------> h. All trans-H2C=CH-CH=CH-OCH3 + H2C=CH-C(O)-H i. 1-bromo-3-chlorobenzene + HNO3/H2SO4 j. CsH5-CH=CH-CH3 + HBr/peroxides --------> H30* k. Ph-CH2-CH3 + KMnO./NaOH/A ----------> L. CoHs-CCl3 + Bry/FeBr ---------- H30* m. Ph-Br + KNH/-33 °C --------
KOIL E1OH Br H, CHi O LLiAIH 2 H,O H,C CH,CH-CHCH.CCH-CHi. CH,CH.OH- CH; HOCH-CH-CH-OH- CH,CH CHCH CCH CH CH, OH CH,CHCH,CH CH (acid catalyst) Clz HCl
KOIL E1OH Br H, CHi O LLiAIH 2 H,O H,C CH,CH-CHCH.CCH-CHi. CH,CH.OH- CH; HOCH-CH-CH-OH- CH,CH CHCH CCH CH CH, OH CH,CHCH,CH CH (acid catalyst) Clz HCl
E) V 57. Identify the best product for the reaction. NH2 1. NaNO2, HCI, O C 2. CuCN A) CHANH B) NH₂ CEN D) CH= H
10 dd.) Br XS NBS CCL, A C Br ee. S0₂H 1. fuming H2SO4 2. HNO/H2SO4 3. Zn(Hg). HCI, A u ff.) OH HO ,Ph 1. H.CrO lacetone 2. PrMgl/Et20 3. H2O* gg.) HO3S. NH2 SQ3H -NH2 SO, H2SO4 303H hh.) OEt -CH₂-OH 1. LiAlH./Et20/ -78 °C 2. H2O il.) Ph Ph 1. Li/Et, 2. Ph Co 3. H,0 Pn
hh.) OEt 1. LIAIHJE!,0/-78 °C 2. H,0 1. LIELO 2. Ph.CO 3.H30 Br 1. Mg/THF 2. formaldehyde 3. NHCl(aq) kk.) 2 Na, EtOH, NH CH,BF mm.) SOH 2 Na, EtOH, NH, nn.) NOZ H2SO4(conc) HNO3(conc) NO 00.) 1. SO, H,SO 2. NaOH/KOHA 3. H,0*
o Mg2+ Br 1 M Ý H2SO4/H20 H,80,140 + H2O + Mg2+ Br HSO4 2. + NaOH NaOH Nal нон a = Proton transfer b= Lewis acid/base c= Radical chain substitution d = Electrophilic addition e=E1 Elimination f=E2 Elimination g=Syl Nucleophilic substitution h=SN2 Nucleophilic substitution Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. 2. 1 Low Hoo H2SO4 i Ho HO 130° NaOH...
Ochem 2 ch 22
Ch 22 Amines (100 pts) Chemistry 2320 p) H&NO3/H2SO 1) Fe, HCI 2) NaOH H2N 1) H2NOg/H,SOA CUCN 2) NaNO2 H2SO4 г) 1) NaNO2 H2SO4 1) H2NO3/H2SO4 2) Fe, HCI 2) HBF4 6. Provide the most efficient synthesis possible by matching the reagents to the reaction. Write the letter(s) over or adjacent to the corresponding reaction arrow. As many as three steps represented by each letter may be needed. Assume intermediate products are isolated and purified...
please write the steps needed to get this product.
A NaBH4/H:0 S KMnO4 HNO3 H2SO4 K HNO3 H2SO4 B LiAlH4/H:07 T CH3MgBr/H:0* U 1. LDA/ 2. CH Br C Dess-Martin L Nal D CrOz/H:07 M H3PO4 V NaCN E H/Pd N Bry/FeBr3 W NH 0 CH:COCI/AICI: X CH3NH2 P CH:CH-CT/AICI: Y SOCI: F SnCl/H30* 1. Hg(OAc)2, H2O/THF G 2. NaBHA HH2SO4, H2O, HgSO4 1. BH3, THF 2. H2O2, OH Q H3O+/H20 Z CH OH R KOH O CHICHI CH3CH CH:CH-C-OH...
RM-Q14 What is the product of the following reaction? o 1) КОН 2) Br N-H ? 3) H,0 4) dilute NaOH CH, NH, A) B) C) D) Select an answer and submit. For keyboard navigation, use the up/down arrow keys to select an answer. a A) b B) с C) d D) RM-Q36 Identify the sequence of reactions that will accomplish the following transformation in high yield. 1) CI AICIS A) - 2) Br2, FeBry AICI: O B) 1) CI...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
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