Question

Give an IUPAC name for the compound below.

Give an IUPAC name for the compound below.

Accepted names for branched allkyl groups are isopropyl, isobutyl, sec-butyl. and tert-butyl.

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Give an IUPAC name for the compound below.

Accepted names for branched alkyl groups are isopropyl, isobutyl, seo-butyl, and tert-butyl.

image.png



How many monochloro substitution products are produced when the alkanes below are chlorinated?

Consider constitutional isomers only, ignore stereoisomers.

a)

image.png The number of monochloro substitution products is _______ 

b)

image.pngThe number of monochloro substitution products is _______ 



In radical chlorination of alkanes, non-equivalent hydrogens react with chlorine atoms at different rates. At 35°C, primary, secondary, and tertiary C-H bonds react at relative rates of 1: 3.9: 5.2 respectively.

These are conditions of kinetic control where product ratios are determined by relative rates of formation. For example, If A is formed twice as fast as B, the A B product ratio will be 2.

Consider chlorination of the alkane below at 35℃,

image.png

1. Specify the tnost reactive C-H bond(s), a-c. _______ 


2. Specify the rite of chlorination in the major monochloro substitution product, a-c. _______ 




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