equation 2 multiply with 3 and subtract equation 1 and 2
2NH3(g) + 3N2O(g) ---------> 4N2(g) + 3H2O(l) H0r = -1010KJ/mole
3N2O(g) + 9H2(g) --------> 3N2H4(l) + 3H2O(l) H0r = -951KJ/mole
(-) (-) (-) (-) (+)
-----------------------------------------------------------------------------------------------------
2NH3(g) +3N2H4---------> 4N2(g) + 9H2(g) H0r = -59KJ/mole --------->5
equation 4 multiply with 9 and addition equation 4 and 5
2NH3(g) +3N2H4---------> 4N2(g) + 9H2(g) H0r = -59KJ/mole --------->5
9H2(g) + 9/2 O2(g) --------> 9H2O(l) H0r = -2574KJ/mole ----->4
----------------------------------------------------------------------------------------------------------------------
2NH3(g) + 3N2H4(l) +9/2O2(g) ---------> 4N2(g) + 9H2O(l) H0r = -2633KJ/mole -------> 6
subtract of 6 and 3 equations
2NH3(g) + 3N2H4(l) +9/2O2(g) ---------> 4N2(g) + 9H2O(l) H0r =- 2633KJ/mole -------> 6
2NH3(g) + 1/2O2(g) -------------------------> N2H4(l) + H2O(l) H0r = -143KJ/mole
(-) (-) (-) (-) (+)
------------------------------------------------------------------------------------------------------------------------
4N2H4(l) + 4O2(g) ----------> 4N2(g) + 8H2O(l) H0r = -2490KJ/mole
The equation divide by 4
N2H4(l) + O2(g) ----------> N2(g) + 2H2O(l) H0r = -622.5KJ/mole >>>>answer
-------------------------------------------------------------------------------------------------------------------
3. (3 points) Hydrazine (N2H4) can react with oxyger in the following chemical reaction: NaH.(1 +0:0) - N2(g) + 2H20 (1...
(ii) Calculate AH° for the reaction N2H4(1) + O2(g) → N2(g) + 2H2O(1) using the data given below: 2NH3(g) + 3N2O(g) → 4N2(g) + 3H2O(1) N2O(g) + 3H2(g) → N2H4(l) + H2O(1) 2NH3(g) + O2(g) → N2H4(1) + H2O(1) H2(g) + 1/2O2(g) → H2O(1) AH° = -1010. kJ AH° = -317 kJ AH° = -143 kJ AH° = -286 kJ
Calculate AH for the reaction N2H4(0) + O2(g) → N2(g) + 2 H2O(1) given the following data: Equation AH (kJ) 2 NH3(g) + 3 N2O(g) → 4 N2(g) + 3 H2O(l) -1010 N2O(g) + 3 H2(g) → N2H4(1) +H2O(1) -317 2 NH3(g) + 1202(g) → N2H4(1) + H20(1) -143 H2(g) + 1202(g) → H2O(H -286 AH=
4. (3 points) Consider the following enthalpies of reaction: CaCz(s) + 2H20 (Ca(OH)2(s) + CH2(g) AH,º=-127.9 kJ/mol Cas) + 1/20 (g) - Cao(s) AH,º=-635.1 kJ/mol Cal(s) + H200 - Ca(OH) (9) AH,=-65.2 kJ/mol The standard enthalpies of combustion of graphite and C2H2(g) are -393.51 and -1299.58 kJ/mol, respectively. Calculate the standard enthalpy of formation of CaCz(s) at 25°C. Aside on enthalpy of combustion: Please note that the standard enthalpy of combustion will form H200, not H:09), if the substance includes...
3) Titanium dioxide is synthesized in the laboratory by hydrolysis, using the following reaction: TICIA() + 2H2O(l) → TIO (s) + 4HCl(s) AH -763 -187.6 945 92.31 What change in internal energy would occur at 298K if 1 mol of TiCl(l) were added to H2O(l) and all of the HCI evolved as gas? 4) Find the molar enthalpy of this reaction: N2H4(0) + H2(g) → 2NH3(g) Given: N,He(l) + CH,OH() → CH2O(g) + N2(g) + 3H2(g) AH -37 kJ N2(g)...
1. Hydrazine is used to remove dissolved oxygen from the water in water heating systems. N2H4(l) + O2(g) à 2H2O(l) + N2(g) What is the free energy changed observed when 1.00 mole of N2H4 is oxidized? (for hydrazine ∆G°f = 149.2 kJ/mol) What is the free energy change for the oxidation of 1.00 pound (454 g) of hydrazine? 2. Calculate the standard free energy change and equilibrium constant for the following reaction at 25 °C. 4Ag(aq) + O2(g) + 4H+(aq)...
What is AHin for the following chemical reaction? CS2(g) + 2H20(1) - CO2(g) + 2H2S(g) You can use the following table of standard heats of formation (AH) to calculate the enthalpy of the given reaction Element Compound Element Compound Standard Heat of Formation (kJ/mol) 218 Standard Heat of Formation (kJ/mo!) 473 0 285.8 H(g) H2(g) H2O(1) CS2(g) C(g) C(s) N(8) 02 (8) 0(g) H2S(g) CO2(g) HNO3(aq) 116.7 249 20.60kJ 393.5kJ 206.6 Express the standard enthalpy of reaction to three significant...
Answer the following questions ans please show your calculation. = 24,7 +402.8 = 1 AH,º= -447KJ AH2O= -484KJ AH;O= -429KJ AHRO= HW12 Using the following reactions: A+B+ 2C LA +3D+ 2E 2D+B+ 2F Calculate AH for the process 4E+ 5B → 4C +6F HW13 Using the following reactions: N2(g) + O2(g) → 2NO(g) N2(g) + 3H2(g) + 2NH3(g) 2H2(8) + O2(g) → 2H20(8) Calculate AH for the process 4NH3(g) + 502(8) → 4NO(g) + 6H2O(8) AH =+180.6 kg AH,O= -91.8...
1. Consider the reaction: 2NH3(g) → N2(g) + 3 H2 (8) AG = +33.3 kJ a. Is this reaction spontaneous? Explain. b. Predict the sign of AS. Explain. C. Based on your answer to part b, is this reaction exothermic or endothermic? Explain. For the reaction N2(g) + 3H2(g) 2NH3 (8) a. Using values in Appendix Cin your book, calculate AHⓇ and AS. b. Assuming that AHºand ASº don't change with temperature, calculate the value for AG at 400K Is...
8. (3 points) Consider the following reaction: N2 (g) +3H2 (g) 2NH3 (g). Find the desired values given the following conditions: PNH3 2.00 atm, PN2 2.00 atm, and PH2 -2.50 atm. The AGo -33.3 kJ/mol at 25 °C. Calculate the Q value for these conditions. a. b. Calculate the AG value for these conditions. c. Is the reactions more or less spontaneous under these conditions compared to the standard conditions? How do you know?
A chemist measures the enthalpy change AH during the following reaction: 3 N2(9) + 8H2(9)→ 4NH3(g) + N,H.(1) AH=-134. kJ Use this information to complete the table below. Round each of your answers to the nearest kJ/mol. reaction AH NH,() +,() - N,(6) + H_() X 5 ? 4NH, (g) + N,H.(1) 3N, (g) + 8H,() k 3 z N. (8) + 4H, (p) + 44,() + 2NH3(g) + ŹN,H,()