Draw the organic product (if any) expected from the following reaction: (include all hydrogen atoms) CH3CH2CH2OH + K2C...

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Answer 1

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Answer #1

Concepts and reason

The problem is based on the concept of oxidation of alcohol.

Oxidation of alcohol with strong oxidizing reagent results in the formation of carboxylic acid.

Fundamentals

An oxidizing reagent has the ability to gain electrons. Therefore, it reduces itself and oxidize the other compound. The reagent, K2CrO2 is a strong oxidizing reagent. It oxidizes primary alcohol to carboxylic acid.

Consider the reaction for the oxidation of K2CrO2 as:

К,Сг.о, + Н,SO, —н, С,О,
Сrо, + H,0
4

The reagent Сo,
3 is the strong oxidizing reagent.

Consider the reaction for the oxidation of alcohol as follows:

CH,CH,CH2OHCro,>CH,CH,CHO

Consider the mechanism for the oxidation of aldehyde to carboxylic acid as follows:

НО
Нӧ:
O=Cr
ОН
|
CН CH.C
H,SO
Н
CH CHCH
CH CHCH
На
ОН
O=Cr O
ОН
CH,CHC
— ОН
CH CHC
Н
HSO

Consider the reaction for the formation of carboxylic acid as follows:

CH, CH,CH,OH + к, Сr,0, (аg):
HSO
->CH,CH,COOH

Ans:

The organic product from the reaction is as follows:

CH, CH,CH,OH + к, Сr,0, (аg):
HSO
->CH,CH,COOH

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Answer 2

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