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Q-3. If silver atoms follow a face-centered cubic unit cell pattern, what is the length of this unit cell if the atomic radiu
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3)

for FCC:

length of one face diagonal = 4*r

a*sqrt(2) = 4*r

a * 1.4142 = 4*144.4 pm

a = 408 pm

Answer: c

4)

since the cubic cell is Face Centred Cubic, the value of Z=4

Molar mass = 192.2 g/mol

d = (Z*M)/(a^3*NA)

23.3 = (4*192.2)/(a^3*(6.022*10^23))

a^3 = 5.479*10^-23 cm^3

a = 3.798*10^-8 cm

a = 379.8 pm

Now use:

length of one face diagonal = 4*r

a*sqrt(2) = 4*r

379.8 * 1.4142 = 4*r

r = 134.3 pm

Answer: a

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