Question

acb ta 2(Ry) RY Ry --). 수(욕-1)n Find the deniumtive for The stater of equalion of DIETERICI s P (Vm-b) RTe RTVm using the Taylor s Serie we obtain 2-ab a 2(2T) 1b- Vm R.T Caladete (37), T . Demonstrate the result obtained for When V-> co and Tbo

Answer 1

State of e f Dieterici P(Vm-b RT e a RTVm Now ext- RT a ATVm) (9-n) Side Cooth taking la Vm b) PLoy (RT)- RTVm find Now olT afifferentiate both Sidle taking Volume = Const T o)- RVm dP dT r2 T T dP a R Vm T2 P Ans 2 RTVm V

UNIRANK to fin d Now by differen tiate both side Temf Const. ei RT dp a KTV Vm T to find Now erO cifferentiate both side taking P- Cm9 a 9-A R T 2 [#J구, JVm a a RTV a + RT2 Vm a KTV Vom"b

Now dVm Ch ra When uhem T Now for YT 7 aT -h when