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Question 3 (6+4 = 10 marks) The five reactions below make up the mechanism for a gas-phase reaction Cl2(g)2 Cl (g) Cl (...
The following mechanism has been proposed for the gas-phase reaction of chloroform (CHCl3) and chlorine. Cl2...
The following mechanism has been proposed for the gas-phase reaction of chloroform (CHCl3) and chlorine. Cl2 ⇌ 2Cl (fast, reversible) Cl + CHCl3 → HCl + CCl3 (slow) Cl + CCl3 → CCl4 (fast) What rate law does this mechanism predict? (Choose from the list below and enter your answers in alphabetical order, e.g. ABC ). A)k G) [CHCl3]1/2 M) [CCl3]2 B) [Cl2] H) [CCl3]1/2 N) [HCl]2 C) [Cl] I) [HCl]1/2 O) [Cl2]2 D) [CHCl3] J) [Cl2]1/2 P) [Cl]2 E)...
Consider the following two-step mechanism for a reaction: NO2(g)+Cl2(g)→ClNO2(g)+Cl(g)Slow N O 2 ( g ) +...
Consider the following two-step mechanism for a reaction: NO2(g)+Cl2(g)→ClNO2(g)+Cl(g)Slow N O 2 ( g ) + C l 2 ( g ) → C l N O 2 ( g ) + C l ( g ) S l o w NO2(g)+Cl(g)→ClNO2(g)Fast a)What is the overall reaction? Express your answer as a chemical equation. Identify all of the phases in your answer. b)Identify the intermediates in the mechanism. Check all that apply. Check all that apply. NO2(g), ClNO2(g), Cl2(g) ,Cl(g)...
The following mechanism has been proposed for the gas-phase reaction of chloroform (CHCl3) and chlorine. Cl2...
The following mechanism has been proposed for the gas-phase reaction of chloroform (CHCl3) and chlorine. Cl2 ⇌ 2Cl (fast, reversible) Cl + CHCl3 → HCl + CCl3 (slow) Cl + CCl3 → CCl4 (fast) What rate law does this mechanism predict? (Choose from the list below and enter your answers in alphabetical order, e.g. ABC ). A)k G) [Cl2]1/2 M) [CHCl3]2 B) [CCl3] H) [Cl]1/2 N) [CCl3]2 C) [HCl] I) [CHCl3]1/2 O) [HCl]2 D) [Cl2] J) [CCl3]1/2 P) [Cl2]2 E)...
A three-step mechanism has been suggested for the formation of carbonyl chloride: Step 1: Cl2 ===> 2 Cl (fast equlibrium) Step 2: Cl + CO ===> COCl (fast equilibrium) Step 3: COCl + Cl2 ===> COCl2 + Cl (slow) What is the molecularit
1. A three-step mechanism has been suggested for the formation of carbonyl chloride: Step 1: Cl2 ===> 2 Cl (fast equlibrium) Step 2: Cl + CO ===> COCl (fast equilibrium) Step 3: COCl + Cl2 ===> COCl2 + Cl (slow) What is the molecularity of the rate-determining step? unimolecular bimolecular termolelcular none of these 2. The elementary reaction representing the formation of ozone, O2(g) + O(g) + M(g) ===> O3(g) + M*(g) is an example of a _________ reaction. unimolecular...
The following mechanism has been proposed for the gas-phase reaction of H2 with ICl: H2(g)+ICl(g)→HI(g)+HCl(g)HI(g)+ICl(g)→I2(g)+HCl(g) c)...
The following mechanism has been proposed for the gas-phase reaction of H2 with ICl: H2(g)+ICl(g)→HI(g)+HCl(g)HI(g)+ICl(g)→I2(g)+HCl(g) c) Write rate laws for each elementary reaction in the mechanism?Use a for [H2], b for [ICl] and k1 for the rate constant. d) Use c for [HI], d for [ICl] and k2 for the rate constant? e) If the first step is slow and the second one is fast, what rate law do you expect to be observed for the overall reaction? Use a...
1) 2) 3) 4) The equilibrium constant for the gas phase reaction 2803 (g) = 2802...
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The equilibrium constant for the gas phase reaction 2803 (g) = 2802 (g) + O2 (g) is Keg = 7.1 x 102 at 999 K. At equilibrium,_ O only reactants are present O roughly equal amounts of products and reactants are present products predominate only products are present reactants predominate QUESTION 20 The rate law of a reaction is rate = k[X]-. The units of the rate constant are O mol L-15-2 OL mol-15-1 O mol2...
in LINE ANGLE format please Polymersti 2. Write the reaction mechanism (showing arrows) of the synthesis of polyst...
in
LINE ANGLE format please
Polymersti 2. Write the reaction mechanism (showing arrows) of the synthesis of polystyrene. 4pts • Include and show arrows in 2 initiation steps with benzoyl peroxide forming the phenyl radical. (this is shown in Figure 9 of the lab- just add all arrows) A propagation step of the styrene (the monomer) and phenyl radical. A second propagation step showing polymer growth by reacting styrene and the radical product of first propagation step. A termination step...
6 (a) N2Os decomposes in the gas phase by the reaction: 2 N2Os (g)4 NO2 (g)+02 (g) At 25°C, a sample of gaseous N2Os sh...
6 (a) N2Os decomposes in the gas phase by the reaction: 2 N2Os (g)4 NO2 (g)+02 (g) At 25°C, a sample of gaseous N2Os showed the following dependence of concentration on time: IN:Os(mmol dm Time/h C0 8.0 5 4.3 10 2.3 15 1.20 0.64 20 ( Determine the order of reaction by plotting an appropriate graph. [5 marks] [2 marks] (ii) Determine the rate constant for this reaction. (ii) Find the concentration of NO2 after 25 h. [2 marks]
6...
ch 14 answer each of these. answer all 3 please HI HCI reactants Reaction intermediates are...
ch 14 answer each of these.
answer all 3 please
HI HCI reactants Reaction intermediates are species that are formed in one step of a mechanism and consumed in another step. For example, can act as an intermediate in the following reaction: H2(g) + 2Cl(g) + 2HCl(g) + 12(g). You can often express the concentration of in terms of the concentrations of the of the overall reaction to be consistent with the experimentally observed rate law as the overall reaction...
please help answer question 4, a-f please using the data below from chart 1 objectives from...
please help answer question 4, a-f please
using the data below from chart 1
objectives from lab, thank you
DATA:CA y 3 Ay No3 Part I: Cell Potential of voltaic cells under standard conditions: cell CU CND2 #27 14.0m Give the half Half cell reaction at Combinations Oxidation Reduction E the anode and with [ion] takes place Theoretical takes place cathode. Write in M here here (V) above the arrow E c (V) if it is oxidation or reduction. |-0.340...
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The equilibrium constant for the gas phase reaction 2803 (g) = 2802 (g) + O2 (g) is Keg = 7.1 x 102 at 999 K. At equilibrium,_ O only reactants are present O roughly equal amounts of products and reactants are present products predominate only products are present reactants predominate QUESTION 20 The rate law of a reaction is rate = k[X]-. The units of the rate constant are O mol L-15-2 OL mol-15-1 O mol2...
in
LINE ANGLE format please
Polymersti 2. Write the reaction mechanism (showing arrows) of the synthesis of polystyrene. 4pts • Include and show arrows in 2 initiation steps with benzoyl peroxide forming the phenyl radical. (this is shown in Figure 9 of the lab- just add all arrows) A propagation step of the styrene (the monomer) and phenyl radical. A second propagation step showing polymer growth by reacting styrene and the radical product of first propagation step. A termination step...
6 (a) N2Os decomposes in the gas phase by the reaction: 2 N2Os (g)4 NO2 (g)+02 (g) At 25°C, a sample of gaseous N2Os showed the following dependence of concentration on time: IN:Os(mmol dm Time/h C0 8.0 5 4.3 10 2.3 15 1.20 0.64 20 ( Determine the order of reaction by plotting an appropriate graph. [5 marks] [2 marks] (ii) Determine the rate constant for this reaction. (ii) Find the concentration of NO2 after 25 h. [2 marks]
6...
ch 14 answer each of these.
answer all 3 please
HI HCI reactants Reaction intermediates are species that are formed in one step of a mechanism and consumed in another step. For example, can act as an intermediate in the following reaction: H2(g) + 2Cl(g) + 2HCl(g) + 12(g). You can often express the concentration of in terms of the concentrations of the of the overall reaction to be consistent with the experimentally observed rate law as the overall reaction...
please help answer question 4, a-f please
using the data below from chart 1
objectives from lab, thank you
DATA:CA y 3 Ay No3 Part I: Cell Potential of voltaic cells under standard conditions: cell CU CND2 #27 14.0m Give the half Half cell reaction at Combinations Oxidation Reduction E the anode and with [ion] takes place Theoretical takes place cathode. Write in M here here (V) above the arrow E c (V) if it is oxidation or reduction. |-0.340...
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