MASS SPECTRUM 100 80- m/z 150 60 40 0.2 20. 00 1000 4500 2500 2000 150) 000 3500 3000 0.0+ 0.0 Wavenurbers (cm-1) on 1...
Fall 2019 Problem 5 IR Spectrum (quid fim) 1715 4000 3000 2000 1600 1200 V (cm) 800 100 44 80 Mass Spectrum 60 58 20 M 71 86 C5H100 40 80 280 120 240 160 200 13C NMR Spectrum (20.0 MMz, CDCI, solution) -сн, C-H proton decoupled TMS C-H solvent Jul. 5 (ppm) 0 120 80 160 200 1H NMR Spectrum (100 MHz, CDCI, solution) expansion of 400 MHz spectrum 20 Hz TMS 0.99 ppm 2.21 2.31 9.75 1 8...
Compound 2 IR Spectrum Chri) 4000 3000 2000 18001200 vom",000 1200000 100 Mass Spectrum UV Spectrum M 220 (1) 2. max 253 nm 0091626) 2. max 250 nm (09, 2.7) 2. max 264 nm (09,06 2.5) PS.... CH2O3 solvent thanol 40 80 120 160 200 240 280 13C NMR Spectrum (100 MHE COCI, solution) DEPT CH CH CH proton decoupled 30 128 ppm 200 - 160 120 80 40 08 (ppm) 'H NMR Spectrum (400MHE. COCI, solution Exchanges wie Do...
Unknown H415 100 50 1000 1S00 2000 3000 BRVENUMBERI 4000 Unknown H415 ЗН 1 H-N 2H, q 1H, d 5H, m 1H, d 0 1 2 3 6 7 8 10 11 ppm HSP-00-049 Unknown H415 q 140 120 100 200 180 160 ppm CDS-00-726 20 -40 60 80 Relative Intensity 09 Unknown H415 100 MS-NJ-0442 80 20 thmpt 25 50 75 100 125 150 175 m/z Date: Name: Section/Group: Instructor: Report Sheet: Laboratory 14 MS,IR, 13C NMR, and 'H...
Please intereperet all spectra fully. Solid U IR Mass Spec. Mt 100- 80 60- 40 0 50 75 100 150 175 m/z Solid U H-NMR doublet, 2H doublet, 2H broad singlet, 1H PPM "C-NMR PPM Solid Unknown Information: Unknown #: Melting Point Infrared Analysis: Explain below how the infrared spectrum led you to select the functional group present in your unknown. Remember, your unknown must belong to one of the following functional groups: alcohol, aldehyde, amine, carboxylic acid, ketone, or...
Use the mass spectrum and either the NMR spectrum or the IR spectrum to deduce the structure of the following compound (c) C8HO3H NMR, 300 MHz, 6.1 ppm (singlet, 2H), 6.9 ppm (doublet, 1H), and 7.3 ppm (singlet, 1H), 7.4 ppm (doublet, 1H), 9.8 ppm (singlet, 1H); significant IR absorbances at 1687, 1602, 1449, 1264, 1038, 929, and 815 cm1. 100 149 (150) 80 60 40 121 63 20 65 91 0 15 20 25 30 35 40 45 50...
Spectroscopy Unknown. The spectra and data provided were obtained from a pure organic molecule. For 1 H NMR Spectra, the integral is given in number of hydrogens (#H) or as a relative ratio. Important coupling constants (J-values) are listed next to the peaks for some examples. For some spectra, an inset (grey box) is also given showing a “zoom-in” on an important part of the spectrum. Mass Spectrum (not shown): [M] = 169 (100%) m/z IR Spectrum (not shown): 2985,...
do the spec problem Problem 9 IR Spectrum (kuid im) 0.0 800 1600 1200 2000 V (cm) 3000 4000 Mass Spectrum 0.5F 100 80 60 UV spectrum 1,0 77 107 5.815 mg/ 10 mls path length: 1.00 cm solvent: ethanel M 122 20E 1.5 300 350 250 200 200 280 240 120 160 40 80 (nm) m/e 13C NMR Spectrum Aath (20.0 MHz, CDCI, solution) expansion x5 off-resonance decoupled proton decoupled 200 160 120 80 8 (ppm) 40 0 1H...
Problem 79 4000 3000 2000 1600 1200 800 V (cm) Mass Specrum uv Spectrum 100 80 60 40t 3 20 max 260 nm (logroE 2.5) 91 solvent: methanol C11H16 40 80 120 160 200 240 280 m/e 13C NMR Spectrum (50.0 MHz, CDC, solution) proton decoupled 200 160 120 40 0 δ(ppm) H NMR Spectrum (200 MHz, CDci, solution) 7.5 7.0 ppm
A compound of unknown structure gave the following spectroscopic data: Mass spectrum: M+ = 88.1 IR: 3600cm-1 1H NMR: 1.4 (2H, quartet, J=7Hz); 1.2 (6H, singlet); 1.0 (1H, singlet); 0.9 (3H, triplet, J=7Hz) 13C NMR: 74, 35, 27, 25 a. assuming that the compound contains C and H but may or may not contain O, give three possible molecular formulas. b. how many protons (H) does the compound contain? c. what functional group(s) does the compound contain? d. how many...
draw the structure for the spectroscopy and show steps and label each part Mass Spectrum (not shown): [M] = 302 (75%), 304 (100%), 306 (25%) m/z (all listed are strong (s) unless otherwise IR Spectrum (not shown): 3090, 2985, 2850, 2750, 1715, 1610, 1500 cm indicated) 'H NMR Spectrum (400 MHz, CDCI, 25 °C) t(J = 2 Hz) t(J= 2 Hz) +(J= 2 Hz) 2H 6H 3H 1H 1H 1H PPM HC NMR Spectrum (with DEPT), proton-decoupled (125 MHz, CDCI,...