Both the gases were sent into the same flask of volume =24.5L
So let us calculate the partial pressure of each gas when it occupies 24.5L at same temperature.
PH2
P1V1= P2V2
3.68atm x3.14 L = P2 x 24.5L
Thus New pressure of H2 =0.4716 atm
similary partial pressure of N2
P1V1= P2V2
4.53atm x 3.89L = P2 x 24.5L
Thus new pressure of N2 = 0.7192 atm
According to Dalton's law
total pressure = sum of partial pressures of gases
= 0.4716 atm + 0.7192 atm=1.191 atm
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