Mun CHEM 2252 Problem Set #2 Vaug 1. Predict the product(s) of the following reactions. Include...
2. Predict the product(s) to the following reactions, pay attention to stereochemistry: (14pt) 1. NaNH2 3. Hº 1. Oa, -78C 2. H20 H, Pd Baso 1. NaNH2 2. Br. 2 H2 HgSO4 H2SO4 1. Sia BH 2. H2Oz/NaOH
1) Predict the major organic product(s) that would result from the following chemical reactions. Pay attention to stereochemistry and apply as needed (8 points). (1) LiAlha, PBr3 KUASA (2) H20 DMSO H2SO4
Predict the major organic product or products of each of the following reactions: Identify the mechanism taking place in each of the reactions and please provide explanation. H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
Draw the major organic product(s) of the following reactions including stereochemistry when it is appropriate. including stereochemistry when it is appropriate. the major organic product(s) of the following reactions CH3 H20/ H2SO4/Hgso4 H3C-C-CEC-CH3 OH
s) Predict the principal organic product(s) in each of the following reactions. Draw the correct stereoisom wherever applicable (Structures with incomplete/wrong stereochemistry will not be accepted!!). CH₃ Clz Br2 Н,0 CCIA 1) BH3. THE 2) H2Oz/NaOH 1) O₃ 2) (CH3)2S МСРВА MCPECIES CH2Cl2 OsO4 NMO 1) МСРВА 2) H2O/H30* Hoy for Hos 1) Brz/H20 2) NaOH 1) Hg(OAC)2, H2O/THF 2) NaBHA = 1) O₃ 2) H20 340 H2SO4 HgSO4 2 Brz CCIA 2 HCI 26. pts) Listed below is information...
1. Draw the product(s) of the following reactions. Include stereochemistry when relevant. If stereoisomers are formed then draw out and label the relationship between your structures. Ph-N3 40°C HN-NH2 SACOMe 150 °C d. CO2CH3 210 °C нсОСН3 In hv ZI 160 °C OBn 85 °C OBn OBno= o 1 equiv. CI K2CO3 heat PhCH N= H 1. LDA (1 equiv.) P 2. Ph Ph 3. aqueous work-up heat EtOH NaOEt 2. Draw the mechanism for the following transformations. I Н...
Predict the products of the following oxidation and reduction reactions. Include stereochemistry when necessary. 1. BH 2. H202, NaOH 3, PCC 4. PhMgBr 5. H20 6. SOCI 1. PBr3 2. Mg OH 3. CH2COCH 4. H+
1. (10 points) Predict the major organic product or products for each of the following. Be sure to include stereochemistry where appropriate. Assume each is in the most appropriate solvent. Remember, "no reaction" may be an answer. a) O3 b) DMS HgSO4 H2SO4 H20 B12 HCI MgBr b) H+
Predict the product or provide the mechanism Predict the Product. Provide the stable organic product(s) for the reactions below. 1. Mgº, CH3CH,OCH CH3 2. CO2 (g) 3. H2O, HCI W MgBr (xs) 2. H2O, HCI 1. K Cr2O7, H2SO4, H2O 2. CH3MgBr (1 eq.) OH 3. H2O, HCI 1. Mgº, CH3CH2OCH2CH3 2. H2O, HCI Mechanism. The following Grignard reaction has been observed to yield products A and B. 1. Me Me MCI THF, -70 °C SOH OH ole er periodo...
1. (9 pts.) Predict the product(s) for the following reactions. Indicate proper stereochemistry when needed. If a mixture of stereoisomers forms, draw each of them. 1) (CH3)2CHCH2MgBr 2) H20 1) LIAIH 2) H,о 1) DIBAL-H 2) H20 CI