Homework Answers
A glycoside is an acetal and is formed by the sugar moeity joined with a non-sugar molecule (aglycone).
glucoside is the glycoside in which the carbohydrate part is glucose.
Thus the basic differe
nce between hemiacetal and glucoside is
glucoside is an acetal not hemiacetal.
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WHAT IS THE DIFFERENCE BETWEEN A HEMIACETAL & A GLUCOSIDE? (draw structures and explain) Use the...
D-Glucose RC +HO-R = H----OH HOP! H -OH нон CH, OH "CH, OH OH HOROR R-C-OR...
D-Glucose RC +HO-R = H----OH HOP! H -OH нон CH, OH "CH, OH OH HOROR R-C-OR R -C-OR + HOH H HO-R Hemiacetal Acetal Aldehyde Alcohol OR 3-436- OHHO- --OR = R'--0 + HO- R R RC-OR + HOH HOR Ketone Alcohol Hemiketal Ketal ch Wired Company CH, OH Сен,он 5. Label the functional group as acetal, ketal, hemiacetal or hemiketal. KOH OH нон a-D-Glucopyranose B-D-Glucopyranose
Map at assify these structures as hemiacetal, hemiketal, acetal, ketal, or other. Each structure needs to...
Map at assify these structures as hemiacetal, hemiketal, acetal, ketal, or other. Each structure needs to go int a box, and they will shrink to fit as needed when you put more than one in a box. Jasperse: Read the hint before you start, because I didn't emphasize the distinction between hemiacetals and hemiketals, or between acetals and ketals. Hemiacetal Hemiketal Acetal Ketal Other ОН OCH3 CH3COCH3 CH2CH3 O II CH3COCH3 OH CH3 | CH3CHOCHZ OCH3 CH3 H3COH H3C CH3...
Classify each of the following as a(n) aldehyde, ketone, ester, hemiacetal, acetal, ketal, cyanohydrin, alcohol, imine,...
Classify each of the following as a(n) aldehyde, ketone, ester, hemiacetal, acetal, ketal, cyanohydrin, alcohol, imine, enamine, enol, hydrate, acid chloride, ester, nitrile, amide, amine, anhydride, carboxylic acid 120 CI blank 1 blank 2 blank 4 blank 3 blank 5 .H O= HO "Н H НО. blank 6 blank 7 blank 9 blank 8 Blank # 1 A/ Blank # 2 A/ Blank # 3 A/ Blank #4 A/ Blank # 5 A/ Blank # 6 A/ Blank #7 A/...
Draw the product of the following reaction between a ketone and an alcohol. Include hydrogen atoms...
Draw the product of the following reaction between a ketone and an alcohol. Include hydrogen atoms in your structural formula. он + H3C-¢-CH3 + HO-CH2-CH3 6-CH2-CH3 How would you classify the product of the reaction? It is an alcohol. + H20 It is a ketone. It is a hemiacetal. It is an acetal.
The hydroxyaldehyde shown cyclizes to form a hemiacetal under acidic or basic conditions. Use wedge-dot structures...
The
hydroxyaldehyde shown cyclizes to form a hemiacetal under acidic or
basic conditions. Use wedge-dot structures to draw the two
stereoisomers formed from the aldehyde when it cyclizes. Explain if
the relationship between the products is the product mixture
expected to be optically active or optically inactive.
The hydroxyaldehyde shown cyclizes to form a hemiacetal under acidic or basic conditions. Use wedge-dot structures to draw the two stereoisomers formed from the aldehyde when it cyclizes. Explain if the relationship between...
C. Review of Lipids 6. Draw the complete reaction for the hydrogenation and saponification of the...
C. Review of Lipids 6. Draw the complete reaction for the hydrogenation and saponification of the triacylglycerol below. Make sure you the reaction is balanced. HC I Hydrogenation reaction using 2 moles of H (9) banoro Saponification reaction os c) a cyclic secondary alcohol biolo wolvo Mode ostin obrolan insand word do Ya d) a tertiary amine that contains no more than 4 carbons. (0) Holmsgniew more nownegosby e) the aromatic isomers of an aromatic ring that contains one hydroxyl...
4. Draw the mechanism for the conversion of 11 to 12. 5. What is the side...
4. Draw the mechanism for the conversion of 11 to 12.
5. What is the side product in the conversion of 12 to 13?
What is the role of the potassium tert-butoxide in the
conversion of 16 to 6?
8. What oxidizing agent is used to convert 17 into 18?
9. In the conversion of 17 to 18 why does the acetal form
between C2-C3 and C5-C6 rather than
C4-C5 or C3-C4?
1. What are 4Å molecular sieves? (Used in...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23,...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...
practice complely the follow, + NaOH following (Fill in the Blanks (ose wnds carboxylic Acid +...
practice
complely the follow, + NaOH following (Fill in the Blanks (ose wnds carboxylic Acid + Amine water carboxylic Aad & Alcohol Carboxylic Acid water Esten + H₂O + tre hydrolysis? Amide + H₂O titre hydedlysis Show the reagent / reagents needed to make the following molecolar conversions. Show reagent (s) to the right. Seach=40 HC=CH₂ HC-CH₃ 4 ة= SH please note: the is an aromated ring. It does not atlect the chemistry Hocao 0 ÖzçēH (oxidation? bacco in there...
D-Glucose RC +HO-R = H----OH HOP! H -OH нон CH, OH "CH, OH OH HOROR R-C-OR R -C-OR + HOH H HO-R Hemiacetal Acetal Aldehyde Alcohol OR 3-436- OHHO- --OR = R'--0 + HO- R R RC-OR + HOH HOR Ketone Alcohol Hemiketal Ketal ch Wired Company CH, OH Сен,он 5. Label the functional group as acetal, ketal, hemiacetal or hemiketal. KOH OH нон a-D-Glucopyranose B-D-Glucopyranose
Map at assify these structures as hemiacetal, hemiketal, acetal, ketal, or other. Each structure needs to go int a box, and they will shrink to fit as needed when you put more than one in a box. Jasperse: Read the hint before you start, because I didn't emphasize the distinction between hemiacetals and hemiketals, or between acetals and ketals. Hemiacetal Hemiketal Acetal Ketal Other ОН OCH3 CH3COCH3 CH2CH3 O II CH3COCH3 OH CH3 | CH3CHOCHZ OCH3 CH3 H3COH H3C CH3...
Classify each of the following as a(n) aldehyde, ketone, ester, hemiacetal, acetal, ketal, cyanohydrin, alcohol, imine, enamine, enol, hydrate, acid chloride, ester, nitrile, amide, amine, anhydride, carboxylic acid 120 CI blank 1 blank 2 blank 4 blank 3 blank 5 .H O= HO "Н H НО. blank 6 blank 7 blank 9 blank 8 Blank # 1 A/ Blank # 2 A/ Blank # 3 A/ Blank #4 A/ Blank # 5 A/ Blank # 6 A/ Blank #7 A/...
Draw the product of the following reaction between a ketone and an alcohol. Include hydrogen atoms in your structural formula. он + H3C-¢-CH3 + HO-CH2-CH3 6-CH2-CH3 How would you classify the product of the reaction? It is an alcohol. + H20 It is a ketone. It is a hemiacetal. It is an acetal.
The
hydroxyaldehyde shown cyclizes to form a hemiacetal under acidic or
basic conditions. Use wedge-dot structures to draw the two
stereoisomers formed from the aldehyde when it cyclizes. Explain if
the relationship between the products is the product mixture
expected to be optically active or optically inactive.
The hydroxyaldehyde shown cyclizes to form a hemiacetal under acidic or basic conditions. Use wedge-dot structures to draw the two stereoisomers formed from the aldehyde when it cyclizes. Explain if the relationship between...
C. Review of Lipids 6. Draw the complete reaction for the hydrogenation and saponification of the triacylglycerol below. Make sure you the reaction is balanced. HC I Hydrogenation reaction using 2 moles of H (9) banoro Saponification reaction os c) a cyclic secondary alcohol biolo wolvo Mode ostin obrolan insand word do Ya d) a tertiary amine that contains no more than 4 carbons. (0) Holmsgniew more nownegosby e) the aromatic isomers of an aromatic ring that contains one hydroxyl...
4. Draw the mechanism for the conversion of 11 to 12.
5. What is the side product in the conversion of 12 to 13?
What is the role of the potassium tert-butoxide in the
conversion of 16 to 6?
8. What oxidizing agent is used to convert 17 into 18?
9. In the conversion of 17 to 18 why does the acetal form
between C2-C3 and C5-C6 rather than
C4-C5 or C3-C4?
1. What are 4Å molecular sieves? (Used in...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...
practice
complely the follow, + NaOH following (Fill in the Blanks (ose wnds carboxylic Acid + Amine water carboxylic Aad & Alcohol Carboxylic Acid water Esten + H₂O + tre hydrolysis? Amide + H₂O titre hydedlysis Show the reagent / reagents needed to make the following molecolar conversions. Show reagent (s) to the right. Seach=40 HC=CH₂ HC-CH₃ 4 ة= SH please note: the is an aromated ring. It does not atlect the chemistry Hocao 0 ÖzçēH (oxidation? bacco in there...
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