1. (15 pts) Give the structure of the major organic product formed in each of the...
3 (24 pts) Give the structure of the major organic product of each of the following reactions, including stereochemistry where appropriate. NaOH methanol-water Он CH-CECH 1. (Sia),BH 2. H,O NaOH OTs NaBr Acetone (OTs Tosylate) NaCN ethanol-water OH Na,Cr,O, H,SO, H,O I н.о H,SO Bra он FeBr NaBH Ethanol
PRACTICE!!! CHEM 3010 Practice exam 3 Give the major product from the following reactions: 2 mol HCI H - C C -CH, B. 2 mol Brz H-CEC-CH3 HCEC-CHE H / Pd on Carbon H/Lindlar Pd H-CECCH 1) NHÀ 2) CH Br HAC-CECH
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
1. (24) Write structural formulas for the major organic product(s) for the following reactions. Be sure to indicate the stereochemistry when relevant. HC CH=CH2 H CH,OH CH2OH 1. Na, liq. NH (b) CH,CH.C=CCH CH3 HẠCH, B, P NH, 2.D2, Pt Cl2 HC CCH2CH=CH CH,CH HCC CH,Cl2 1. BH/THF (d) CH,CH,C=CH2 2. H,02, HO", H0 CH -0.47- CH; Br2 excess NaCl 1. 03,-78°C 2. (CH3)2S woboto (h) + Br₂ -
Draw the structure of the MAJOR ORGANIC compound formed in each reaction. Assume the reactions have been terminated and neutralized. a. Ethyl acetate NaOEVEtOH b. EtO C-CH2-CH2-CH2-CH2.CO2Et NaOEU/HOEt Ph-C(O)-CI c. (HaC).CH-CO2Et LDATHF + HO. d. Ethanal Ph-C(O)-H Ha0* (cat) e. Acetone + H2C O + Et NH f. Triethylamine HBr/H2O g. Ph-C(O)-NH2 + Br2 4 NaOH h. (H,C)2CH-C(CH)2 + N(CHs)s HO i.Ph-N2, Cl- CuCN- Na/E1OH HaO* (cat) j. cyclohexanone H2NOH Pd(OAc)2 (1 mole%) k. Ph- 4-O2N-CeHe-HC=CH2 Cul/Pd(PPhale L.HO-CH2-CH2-C-H1-CH-CH-(CH2),-CHg
CHM230 Class Worksheet Alkene and Alkyne reactions Give the major product of each of the following reactions: CH,CH,C=CH + 1 equivalent HCI H2 + Lindlar catalyst CH3CHCH2C=CCHCH3 + CICH + H+ + CH3CH2OH CH3CH2C=CH + 2 equivalents HCI CH,CH2C=C-CH3 + 2 equivalents HBr + H+ + H2O + excess HBr CH,CH.C=C-CH3 + excess Hy/Lindlar 2 + excess H/PUC CH3C=C-CH3 + H2O / H / Hg2+ ox.. + HBr + NaNH2 + CH CH Br Given the following alkyne, provide the...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO ROOR Question 2: Draw a mechanism for the following transformations: a) H₃C CH3 HCI H₂C T CH3 HAC CH3 нс с Question 3: Draw the mechanism for the following transformations: нс сH3 CH3 о (H,SO4), он H₂C7 Question 4 HĄCE 1) Hg(OAC), H, 2) NaBH, HEC CH, Question : Predict the product(s) of the following reaction: 1) BHZ. THE Н4С SCH, 2) H2O, NaOH...
Give the major product from the following reactions: 2 mol HCI H-CEC-CH3 B. 2 mol Br2 H-CEC-CH3 H/Pd on Carbon H- C= C—CH3 H/Lindlar Pd H-CEC-CH3 1) NH) 2) CH Br H2C-CECH
1. (20 pts) Give the structure of the major organic product (including stereochemistry if appropriate) formed in each of the following reactions. SOCI CH,CO,H (peroxyacid) PCC CH.CZ • PCC = Pyridinium Chlorochromate Nah Benzene AICI Na,Cr, H,so, (aq) heat Zn(Hg) HCI heat NASH Ethanol-Water Continued on opposite sido
What major Organic product is formed after the following sequence of reactions? 1) NaH, THF 2) Br Br B1 (C) (b) Br Bi a. a Considering both regiochemistry and stereochemistry, what is the major Organic product of the following reaction? о ні. CH-CH, НСІ Снон HC "CH; но CH, НО CH, HCO CH-CH; CH «CH-CH, OCH; CH CH3 ОН нс СІ H; Н;С (6) (c) H.CO CH, Kotic CH.CH НО CH; Но CH.CH Сн, НП). CH,CH; ОН нс Н.С осн;...