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2. Lead poisoning. Treatment for lead poisoning provided by intravenous injection of EDTA in the blood of patient. The concen

can someone give step by step calculations with neat handwriting

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Answer #1

The balanced chemical reaction for the complex formation is

Pb2+(aq) + EDTA4-(aq) ------- > Pb(EDTA)2-(aq) : Kf = 2.0x1018   

Given [EDTA4-(aq)] = 1.0x10-7 M

Kf = 2.0x1018 = [Pb(EDTA)2-(aq)] / [Pb2+(aq)]x [EDTA4-(aq)]

=> 2.0x1018 x [EDTA4-(aq)]  =  [Pb(EDTA)2-(aq)] / [Pb2+(aq)]

=> [Pb(EDTA)2-(aq)] / [Pb2+(aq)] =  2.0x1018 x 1.0x10-7 M = 2.0x1011

=>  [Pb2+(aq)] (free) / [Pb(EDTA)2-(aq)](complex) = 1 / 5.0x1010 = 5.0x10-12

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