major contributor(s):
A.
B.
C.
D.
E.
minor contributor(s):
A.
B.
C.
D.
E.
2. Identify the major and minor resonance contributor(s) for the formate anion, HCO2–.
major contributor(s):
A.
B.
C.
D.
minor contributor(s):
A.
B.
C.
D.
Different contributing structures of azide ion and formate anion are given. The major and minor contributing structures among the given compounds needs to be given. Consider the octet rule and charge separation for deciding the major and minor contributing structures.
Resonance: The representation of some molecules can be done through several Lewis structures. These different structures of the same molecule are known as contributing structures. A hybrid of the contributing structures represents the real structure of the molecule and is known as resonance hybrid.
Such molecules having different Lewis structures exhibit resonance. Resonance occurs through the delocalization of lone pairs over various atoms within the molecule. Consider the example of nitrite ion:
Stability of the contributing structures:
• The contributing structures having a complete octet or maximum number of covalent bonds are the most stable and contributes maximum towards the resonance hybrid.
• A neutral contributing structure is given preference over structures having formal charge.
• The structures with lesser formal charges and lesser charge separation are more stable.
• The contributing structures having negative charge on more electronegative atom is more stable.
• The contributing structures that have opposite formal charges on adjacent atoms are more stable.
Part 1.
The structures D and E of azide anion are incorrect among the given structures. Hence, the structures D and E are eliminated.
The major structure is C and the minor structures are A and B.
Part 2
The structure D of formate anion is incorrect among the given structures. Hence, the structure D is eliminated.
The major contributing structures are A and B and the minor contributing structure is C.
Ans: Part 1The major and minor resonance contributors for the azide anion are as follows:
1. Identify the major and minor resonance contributor(s) for the azide anion, N3–. major contributor(s): A....
?? Identify the major and minor resonance contributor(s) for the azide anion, N3-.
deee Identify the major and minor resonance contributor(s) for the formate anion, HCO2-
Draw all resonance structures for this molecule and determine the major and minor resonance contributor. Where do you start when there are two groups attached to a benzene ring? :0 CH3
1. Draw all resonance structures for the following compound. Circle the major contributor (to the resonance hybrid) and give a brief explanation for your choice. (4 pts) 2. Determine the configuration (show priorities and work) for any chiral centers in the molecule below. (2 pts) 2. Determine the configuration (show priorities and work) for any chiral centers in the molecule below. (2 pts) 1. Draw all resonance structures for the following compound. Circle the major contributor (to the resonance hybrid)...
3. PRACTICE WITH A TON OF RESONANCE CONTRIBUTOR EXAMPLES! Draw the resonance contributors for the speciesmolecules shown in the boxes below. Then, indicate which species if any) is the MAJOR contributor towards the resonance hybrid (most stable) a. OCH3 C. d HO f. CI 1 1 1 O:
Rank the resonance structures in each row of the table from major to minor. For example, in the first row, select 1 (major) for the major resonance contributor. If two or more structures in the same row contribute equally, rank them equally by selecting the same number. H-N-C=c-H H H–ï=c=č—H (Rank) (Rank) 1 (major) HH Η Η Ć-Ć H-O: H. C + H och :Br: :Br: (Rank) (Rank) v . H–ộ: H h—ö=ċ-ċ-H Hºo H . H-ö——¢-H н Η (Rank)...
Practice Problem 07.76f Identify the major and minor product(s) of the following reaction: If there is more than one minor product, be sure to draw all of them.
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5. Draw the number of resonance structures indicated, your structures must fulfill the octet rule. This exercise serves to develop a sense of which Lewis Structures are reasonable so think whether what you are proposing makes sense. Assign formal charges and determine which structure is more likely, major contributor. Draw a box around this structure. Note: it is possible to have more than one major contributor. In that case, indicate these equivalent structures by drawing a box around all of...