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If 484.7 mL of nitrogen gas, measured at 777.5 mmHg and 88.2oC, reacts with excess iodine...

If 484.7 mL of nitrogen gas, measured at 777.5 mmHg and 88.2oC, reacts with excess iodine according to the following reaction, what mass of nitrogen triiodide is produced?

N2(g) + 3I2(s) → 2NI3(s)

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Answer #1
substrate -----> product
n 2n

moles of N2 in substrate = 2(moles of NI3 )

now for N2
PV = nRT

P = 777.5/760 = 1.023
V = 0.484 L
R = 0.0821
T = 88.2 + 273 = 361.3

so now moles n = PV/RT
n = 1.023 * 0.484 / 0.0821*361.3
= 0.0167 moles

so no of moles of NI3 = 2*0.0167 = 0.0334

molecular wt of NI3 = 394.7

so mass of NI3 formed = moles * mole. wt
= 0.0334 * 394.7
= 13.18 gm
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