first i showed the mechanism of first part and then using this i formed all possible aldol condensation products between aldehydes and ketones. For detailed understanding please go through detailed solution given below.
What are the possible aldol condensation products and structures of the products from this list of...
Aldol-dehydration reaction Please draw all 25 products formed from the reaction of the below ketones and aldehydes. Mechanism is not necessary. acetone cyclopentanone cyclohexanone 4-methylcyclohexanone cycloheptanone H H CHO H CHO Meo benzaldehyde 4-methylbenzaldehyde (p-tolualdehyde) 4-methoxybenzaldehyde p-anisaldehyde E-3-phenylpropenal (cinnamaldehyde) 2-furaldehyde (furfural) Ketone Aldehyde acetone cyclopentanone cyclohexanone 4-Me-cyclohexanone cyloheptanone benzaldehyde 113 °C 189-190 °C 118-119 °C 98-99 °C 106-107°C tolualdehyde 175 °C 233-235 °C 170 °C 134-136 °C 131-133°C anisaldehyde 129-130 °C 212-214°C 160-162 °C 136 °C 128-129°C cinnamaldehyde 144-145 °C...
This experiment was based on Aldol-dehydration reaction using unknown aldehydes and ketones. We carried out an aldol condensation between an unknown aldehyde and an unknown ketone. Here are the list of possible unknown aldehydes and ketones that were used. Here is the NMR of the final product. Please predict the structure given the melting point is 163 degrees Celsius. The analysis of the 1H NMR spectrum should include a detailed assignment of each of the NMR resonances to the protons...
What are the namesof the product of the aldol-dehydration reaction with the given aldehydes (A) and ketones (K)? 1) A = tolualdehyde + K = 4-Me-cyclohexanone 2) A = tolualdehyde + K = cyloheptanone 3) A = anisaldehyde + K = acetone 4) A = anisaldehyde + K = 4-Me-cyclohexanone 5) A = anisaldehyde + K = cyloheptanone 6) A = cinnamaldehyde + K = acetone 7) A = 2-furaldehyde + K = cyclohexanone
Postlab Assignment for Minilab 34 “Preparation of Aldol Condensation Products” 1. Explain why benzaldehyde is expected to be the most reactive aldehyde among the three aldehydes used in this experiment. (used benzaldehyde, 4-methylbenzaldehyde, and 4-methoxybenzaldehyde) 2. What is the role of aqueous NaOH used in the experiment you carried out? 3. How would you change the procedures in this experiment if you wished to synthesize benzalacetophenone (C6H5CH=CHCOC6H5). Just indicate the two main organic starting materials. 4. Write a mechanism for...
Aldehyde: ZPA Ketone: BCK Amount of material started with: 2 mL of aldehyde and 0.5 mL of Ketone Recrystallized Mass: 1.53 g Melting Range: 196-200 C Recrystallization Solvent: 9:1 Ethanol/Acetone 1) structure of product 2)theoretical yield 3)isolated and percent yield 6.1724 7.6069 7.5891 Z-8, CDC13 Z-B, CDC13 7.2839 2724 7.6069 7.5891 4.061 7.0012 6.9836 7.2839 7.2 6.08.18 8862 7.0 4.0666 7.0012 6.9836 3.9987 -3.1154 Ippm] Ippm] component. The possible aldehydes are benzaldehyde, 4-methylbenzaldehyde (p-tolualdehyde), 4-methoxybenzaldehyde (p-anisaldehyde), and E-3-phenyl-2-propenal (cinnamaldehyde). The...
1.Show the structures of possible products formed upon aldol self-condensation of cyclopentanone.
Codes: Aldehyde: ZPA Ketone: BCK Amount of material started with: 2 mL of aldehyde and 0.5 mL of Ketone Recrystallized Mass: 1.53 g Melting Range: 196-200 C Recrystallization Solvent: 9:1 Ethanol/Acetone 6.1724 7.6069 7.5891 Z-8, CDC13 Z-B, CDC13 7.2839 2724 7.6069 7.5891 4.061 7.0012 6.9836 7.2839 7.2 6.08.18 8862 7.0 4.0666 7.0012 6.9836 3.9987 -3.1154 Ippm] Ippm] Aldehydes ketones Cyclopentanone Cyclohexanone Acetone Benzaldehyde p-tolualdehyde p-anisaldehyde Cinnamaldehyde 113 °C 175 °C 129-130 °C 144 °C 189 °C 235-236 °C 212 °C...
Provide a generic mechanism for an aldol condensation. DRAW structures for the 16 possible products.
What is the product of the aldol condensation between cyclopentanone and 4-methoxy-benzaldehyde ? and what is the name of the product
What is the aldol condensation product of benzaldehyde and 4-anisaldehyde? Please show the STRUCTURE, REACTION, NAME OF PRODUCT, AND MECHANISM.