Question
  1. (a) What is the reduction potential of the half reaction in which V2+ is reduced to V?

  2. (b) Give the balanced half equation and accompanying E° value for the reduction half-reaction with the largest (most positive) E° value that involves a pair of species indicated in the Frost diagram.

  3. (c) Indicate which species, if any, will undergo disproportionation.

  4. (d) Give the balanced reduction half-equation and accompanying E° value for the reduction of VO2+ to V2+.

  5. (e) In the Pourbaix diagram for vanadium a diagonal line separates the species VO2+ and V3+. Give the equation of this line, which relates pH and E.time 121 +2 +2 = 8 minutes] Question 8 0) is shown below The Frost diagram for vanadium under acidic conditions (pH Oxidation

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Answer #1

a) 2.36/2 1.18 As frost diagram nE0=-2.36

c) any species of vanadium will not under go the disproportionation process.V02t 2H+2e v2 o n=2 (n-no4 elaetron) -2 V3+-2.27 vozt nE nE2E2 2xE-2-6+(-2-27) -4.88

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