For the following process: H2O(g) + Cl2O(g) à 2HOCl(g) Ho(H2O(g))= 242KJ/mol Ho(Cl2O(g))=80KJ/mol Ho(HOCl(g))= -80KJ/mol So(H2O(g))= 0.189 KJ/K So(Cl2O(g))=0.266 KJ/K So(HOCl(g))= 0.237 KJ/K A) Calculate ΔHo, ΔSo and ΔGo B)Calculate ΔG at 100K and P(H2O)=P(Cl2O)= P(HOCL)=10atm
Draw a mechanism for the following tautomerization.
gran on ar HO H2O
CH4 (g) + O2(g) +H2O-------> CO2 (g) + H2O What would the percent yield of the reaction be if 15.2 g of O2 were reacted and only 6.7 g of CO2 were made?
CI Yre me ins- 19 What reagents would you use to accomplish a substitution reaction with inversion of configuration in the following multi-step process below: Show products and the mechanism of each step of the process. (10) OH CN te enslon H T mit : NEN
The experimental rate law for the reaction 2H2(g) + 2 NO(g) → N2(g) +2 H2O(g) is d[N2) = kods[Hz][NO] Below is a proposed mechanism: H2(g) + NO(g) + NO(g) = N2O(g) + H2O(g) H2(g) + N2O(g) = N2(g) + H2O(g) ki k2 (a) Under what conditions does this mechanism give the observed rate law? Express kobs in terms of the rate constants for the individual steps of the mechanism. A second proposed mechanism is: NO(g) + NO(g) = N2O2(g) N2O2(g)...
At 10 ˚C, the solubility of KNO3 is 30 g/100 g H2O. Would you expect the solubility of KNO3 to be higher or lower at 40 ˚C? Explain. A sample containing 80 g of oxygen gas has a volume of 50 L. What is the volume after 4.00 g of oxygen gas is added to the balloon, if temperature and pressure do not change?
Draw a complete electron pushing mechanism for the following
reaction.
HOA AN Hg2*, H₂SO4 (dil) H2O, A HO) OH HO (10 pts) A)
An example of a nonspontaneous process with negative ∆H0 and negative ∆S0 would be a. H2O(g) -> H2O(l) at 1050C b. H2O(g) -> H2O(l) at 950C d. H2O(l) -> H2O(g) at 1050C e. H2O(l) -> H2O(g) at 950C
What is the mechanism for this reaction?
HO BF3 Et20
Fenton Reaction HO3 + Felt ki Fe+ + + + HO. Fe+ + H2O, k2Fe+ + OH- + OH HO, + Fel+ + Fe2+ + H OH + Fe+ K OH + Fe+ OH + H2O, SHO, . + H2O HQ Felt H₂O + 6 as the 1st ordor of The reaction rate of fenton reaction with the mechanism as above can be expressed reaction rate as below. - d CH₂02] - K [Fe 3+ ] [H₂O₃] = kobs CH,...