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23. (3 pts.) Assign the peaks in the infrared spectrum of triphenylmethanol with frequencies greater than 1500 cm1 to specific bond vibrations AND the functional group the bond is associated with. Clearly indicate the specific bond vibration that is associated with the relevant peaks. 12 LOD 3026 1598 3062 130300 890 SD OH 1157 1450 3464 1010 1445 757 4000 2000 1500 1000 500

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Answer #1

The absorptions above 1500 in the spectrum are 1598 , 3026.3062 and 3464

3464 - this the characteristic O-H str of the alcoholic group.the broad peak shows the presence of H-bonded -OH group.

3062 and 3026 are sp2 C-H stretch

1598 is the typical aromatic ring C=C stretch.

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