Problem

The azide ion, N3 -, is linear with equal N–N bond distances. a. Describe the pi mo...

The azide ion, N3 -, is linear with equal N–N bond distances.

a. Describe the pi molecular orbitals of azide.

b. Describe in HOMO-LUMO terms the reaction between azide and H+ to form hydrazoic acid, HN3.

c. The N–N bond distances in HN3 are given in Figure 8.30 . Explain why the terminal N–N distance is shorter than the central N–N distance in this molecule.

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