If an equimolar mixture of and B(C6F5)3 is mixed with 1 bar of the gas N2O in bromobenzene solution, a white product is formed in good yield. A variety of NMR evidence has been gathered on the product: there is a single 31P NMR resonance; 11B and 19F NMR are consistent with a 4-coordinate boron atom; and 15N NMR indicates two nonequivalent nitrogen atoms. In addition, no gas is released in the reaction.
a. Suggest the role of N2O in this reaction.
b. Propose a structure of the product. (See E. Otten, R. C. Neu, D. W. Stephan, J. Am. Chem. Soc. , 2009 , 131 , 9918.)
We need at least 10 more requests to produce the solution.
0 / 10 have requested this problem solution
The more requests, the faster the answer.